A 5.00-ml. sample of blood was treated with trichloroacetic acid to precipitate proteins. Alter centrifugation, the resulting solution was brought to a pH of 3 and was cxtraccd with two 5-mL portions of methyl isobutyl ketone containing the organic lead complexing agent APCD. The extract was aspirated directly into an air-acetylene flame yielding an absorbance of 0.454 at 283.3 nm. Five-milliliter aliquots of standard solutions containing 0.240 and 0.475 ppm Pb were treated in the same way and yielded absorbancc of 0.412 and 0.642. Calculate the concentration Pb (ppm) in the sample assuming that Beer's law is followed.

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Atomic diffusion in solids

In material science, diffusion can take place in solid, liquid, and gases. In solids, atomic diffusion can take place with the help of thermally activated and randomly vibrating atoms. The atomic diffusion in solids is complex and very slow in comparison to atomic diffusion in liquids and gases because the interatomic distance between the atoms is smaller in solids as compared to liquids and gases.