90. Consider two redox pairs (1) Cr(II)/Ru(III) (2) Cr(II)/Co(III) The rate of acceleration in going from a outer-sphere to a inner-sphere mechanism is lower for (1) relative to (2). Its correct explanation is: (a) HOMO/LUMO are o* and o* respectively. (b) HOMO/LUMO are o* and respectively. (c) HOMO/LUMO are ï* and o* respectively. (d) HOMO/LUMO are * and * respectively.

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90.
Consider two redox pairs
(1) Cr(II)/Ru(III)
(2) Cr(II)/Co(III)
The rate of acceleration in going from a outer-sphere to a inner-sphere mechanism is lower for (1)
relative to (2). Its correct explanation is:
(a) HOMO/LUMO are o* and o* respectively. (b) HOMO/LUMO are o* and * respectively.
(c) HOMO/LUMO are * and o* respectively. (d) HOMO/LUMO are î* and
respectively.
*
Transcribed Image Text:90. Consider two redox pairs (1) Cr(II)/Ru(III) (2) Cr(II)/Co(III) The rate of acceleration in going from a outer-sphere to a inner-sphere mechanism is lower for (1) relative to (2). Its correct explanation is: (a) HOMO/LUMO are o* and o* respectively. (b) HOMO/LUMO are o* and * respectively. (c) HOMO/LUMO are * and o* respectively. (d) HOMO/LUMO are î* and respectively. *
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