21. Sketch one reaction profile that is consistent with all three of the following statements: (a) The starting four-coordinate ML3X reactant complex is inert toward substitution by the ligand, Y. (b) The conversion of ML3X + Y to ML3Y +X is an exothermic process. (c) A five-coordinate ML3XY species is observed during the course of the reaction. etal present in I(CO)] 22. Draw out steps of a mechanism for the dissociative substitution of a CO ligand in Fe(CO)s by a PMe3 ligand to generate Fe(CO)4(PME3). a rule for the
21. Sketch one reaction profile that is consistent with all three of the following statements: (a) The starting four-coordinate ML3X reactant complex is inert toward substitution by the ligand, Y. (b) The conversion of ML3X + Y to ML3Y +X is an exothermic process. (c) A five-coordinate ML3XY species is observed during the course of the reaction. etal present in I(CO)] 22. Draw out steps of a mechanism for the dissociative substitution of a CO ligand in Fe(CO)s by a PMe3 ligand to generate Fe(CO)4(PME3). a rule for the
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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In dissociative pathway first, the metal and ligand bond tends to break fully before the formation of new ligand bond with the metal.
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