21. Sketch one reaction profile that is consistent with all three of the following statements: (a) The starting four-coordinate ML3X reactant complex is inert toward substitution by the ligand, Y. (b) The conversion of ML3X + Y to ML3Y +X is an exothermic process. (c) A five-coordinate ML3XY species is observed during the course of the reaction. etal present in I(CO)] 22. Draw out steps of a mechanism for the dissociative substitution of a CO ligand in Fe(CO)s by a PMe3 ligand to generate Fe(CO)4(PME3). a rule for the

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21. Sketch one reaction profile that is consistent with all three of the following
statements:
(a) The starting four-coordinate ML3X reactant complex is inert toward substitution by
the ligand, Y.
(b) The conversion of ML3X + Y to ML3Y +X is an exothermic process.
(c) A five-coordinate ML3XY species is observed during the course of the reaction.
etal present in
I(CO)]
22. Draw out steps of a mechanism for the dissociative substitution of a CO ligand in
Fe(CO)s by a PMe3 ligand to generate Fe(CO)4(PME3).
a rule for the
Transcribed Image Text:21. Sketch one reaction profile that is consistent with all three of the following statements: (a) The starting four-coordinate ML3X reactant complex is inert toward substitution by the ligand, Y. (b) The conversion of ML3X + Y to ML3Y +X is an exothermic process. (c) A five-coordinate ML3XY species is observed during the course of the reaction. etal present in I(CO)] 22. Draw out steps of a mechanism for the dissociative substitution of a CO ligand in Fe(CO)s by a PMe3 ligand to generate Fe(CO)4(PME3). a rule for the
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In dissociative pathway first, the metal and ligand bond tends to break fully before the formation of new ligand bond with the metal.

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