In the smelting of iron ores, the reduction of iron oxides in a blast furnace is accompanied by the oxidation of COg) to COzg)- The three reactions leading to the formation of Fe are: Reaction (i): 3 Fez031) + CO g) - 2 Fej04e) + CO2(9) Reaction (ii): Fe,O4(a) + CO(g) - 3 FeO(e) + CO2(g) Reaction (ii): Fe0(4) + CO(g) - Fe (s) + C02(g) The graph below shows the variation of the Gibbs energy change with temperature for each of these reactions. Which one of the following statements is INCORRECT? 50 (iii) 40 -50 (ii) -100 (i) -150 1000 2000 TIK O All of the three reactions are spontaneous at 500 K. Reactions (i) and (i) are more favorable at high temperatures. O The Keg for Reaction (i) is larger than the Keg for Reaction (ii) at all temperatures. Reaction (iii) is spontaneous at high temperatures.

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In the smelting of iron ores, the reduction of iron oxides in a blast furnace is accompanied by the oxidation of COg) to CO2g)- The three reactions leading to the formation of Fe are:
Reaction (i): 3 Fe,03e) + CO(g) - 2 Fe,04e) + CO2(9)
Reaction (ii): Fe,04(a) + CO(g) - 3 FeO(e) + CO2(g)
Reaction (ii): FeO(e) + CO(g) - Fe (s) + CO29)
The graph below shows the variation of the Gibbs energy change with temperature for each of these reactions.
Which one of the following statements is INCORRECT?
50
(iii)
40
-50
(ii)
-100
(i)
-150
1000
2000
T/K
O All of the three reactions are spontaneous at 500 K.
Reactions (i) and (i) are more favorable at high temperatures.
O The Keg for Reaction (i) is larger than the Kug for Reaction (ii) at all temperatures.
Reaction (ii) is spontaneous at high temperatures.
Transcribed Image Text:In the smelting of iron ores, the reduction of iron oxides in a blast furnace is accompanied by the oxidation of COg) to CO2g)- The three reactions leading to the formation of Fe are: Reaction (i): 3 Fe,03e) + CO(g) - 2 Fe,04e) + CO2(9) Reaction (ii): Fe,04(a) + CO(g) - 3 FeO(e) + CO2(g) Reaction (ii): FeO(e) + CO(g) - Fe (s) + CO29) The graph below shows the variation of the Gibbs energy change with temperature for each of these reactions. Which one of the following statements is INCORRECT? 50 (iii) 40 -50 (ii) -100 (i) -150 1000 2000 T/K O All of the three reactions are spontaneous at 500 K. Reactions (i) and (i) are more favorable at high temperatures. O The Keg for Reaction (i) is larger than the Kug for Reaction (ii) at all temperatures. Reaction (ii) is spontaneous at high temperatures.
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