Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Department of Chemistry/UNK**
**8. Write the main product for the following elimination reactions:**
1. Cyclohexane compound with substituents:
- Br, H, Et (Ethyl), Pr (Propyl)
- Reacts with: NaOCH₃, MeOH/heat
- → Product
2. Linear alkane with tosylate (OTs) group:
- Reacts with: NaOCH₃, MeOH/heat
- → Product
3. Branched alkane with tosylate (OTs) group:
- Reacts with: KOtBu, HOtBu/heat
- → Product
4. Bicyclic compound with Cl substituent:
- Deuterium (D) indicated
- Reacts with: NaOCH₃, MeOH/heat
- → Product
---
Explanation of Diagram:
1. The first reaction features a cyclohexane ring with different substituents. The transformation involves elimination using sodium methoxide (NaOCH₃) in methanol with heat.
2. The second diagram is an alkane chain featuring a tosylate (OTs) leaving group, subjected to elimination under the same conditions.
3. The third structure is a branched alkane also with a tosylate group, eliminating with potassium tert-butoxide (KOtBu) in a tert-butanol (HOtBu) solvent with heat.
4. The final structure is a bicyclic compound with a chlorine substituent and a deuterium atom, eliminating under conditions similar to reaction one.
These reactions generally form alkenes through the elimination of halides or tosylates."
Transcribed Image Text:Transcription of the Image:
---
**Department of Chemistry/UNK**
**8. Write the main product for the following elimination reactions:**
1. Cyclohexane compound with substituents:
- Br, H, Et (Ethyl), Pr (Propyl)
- Reacts with: NaOCH₃, MeOH/heat
- → Product
2. Linear alkane with tosylate (OTs) group:
- Reacts with: NaOCH₃, MeOH/heat
- → Product
3. Branched alkane with tosylate (OTs) group:
- Reacts with: KOtBu, HOtBu/heat
- → Product
4. Bicyclic compound with Cl substituent:
- Deuterium (D) indicated
- Reacts with: NaOCH₃, MeOH/heat
- → Product
---
Explanation of Diagram:
1. The first reaction features a cyclohexane ring with different substituents. The transformation involves elimination using sodium methoxide (NaOCH₃) in methanol with heat.
2. The second diagram is an alkane chain featuring a tosylate (OTs) leaving group, subjected to elimination under the same conditions.
3. The third structure is a branched alkane also with a tosylate group, eliminating with potassium tert-butoxide (KOtBu) in a tert-butanol (HOtBu) solvent with heat.
4. The final structure is a bicyclic compound with a chlorine substituent and a deuterium atom, eliminating under conditions similar to reaction one.
These reactions generally form alkenes through the elimination of halides or tosylates.
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