7. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride asshown below:(CH3)3COH(aq) + H¯(aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1)For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate lawconsistent?A) (CH3)3COH(aq) + H*(aq)(CH3)3C(OH₂)*(aq)B)(CH3)3C(OH₂)*(aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1)(CH3)3COH(aq) → (CH3)3C+(aq) + OH-(aq)(CH3)3C+ (aq) + Cl(aq) → (CH3)3CCl(aq)H*(aq) + OH-(aq) → H₂O(1)(CH3)3COH(aq) + Cl·(aq) → (CH3)3CCl*(aq) + OH¯(aq)H*(aq) + OH-(aq) → H₂O(1)(CH3)3COH(aq) + H*(aq) → (CH3)3C(OH₂)*(aq)(CH3)3C(OH₂)*(aq) → (CH3)3C¯(aq) + H₂O(1)(CH3)3C+(aq) + Cl(aq) → (CH3)3CCl(aq)E) None of these mechanisms are consistent with the rate law provided.C)D)(fast)(slow)(slow)(fast)(slow)(fast)(fast)(fast)(slow)(fast)

Answered: Image /qna-images/answer/e79327b3-435d-41cd-b99d-5ab84c04c58c.jpg

7. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as shown below: (CH3)3COH(aq) + H*(aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1) For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate law consistent? A) (CH3)3COH(aq) + H*(aq) → (CH3)3C(OH₂)*(aq) (CH3)3C(OH₂) (aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1) B) (CH3)3COH(aq) → (CH3)3C+(aq) + OH-(aq) (CH3)3C+(aq) + Cl·(aq) → (CH3)3CCl(aq) H*(aq) + OH-(aq) → H₂O(1) E) (fast) (slow) C) (CH3)3COH(aq) + Cl·(aq) → (CH3)3CCl(aq) + OH-(aq) H+ (aq) + OH-(aq) → H₂O(1) D) (CH3)3COH(aq) + H+(aq) → (CH3)3C(OH₂) (aq) (CH3)3C(OH₂)*(aq) → (CH3)3C¯(aq) + H₂O(1) (CH3)3C+ (aq) + Cl(aq) → (CH3)3CCl(aq) None of these mechanisms are consistent with the rate law provided. (slow) (fast) (slow) (fast) (fast) (fast) (slow) (fast)

7. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as shown below: (CH3)3COH(aq) + H(aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1) For this reaction, rate = k[(CH3)3COH][H]. With which mechanism is this rate law consistent? A) (CH3)3COH(aq) + H(aq) → (CH3)3C(OH₂)(aq) (CH3)3C(OH₂) (aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1) B) (CH3)3COH(aq) → (CH3)3C+(aq) + OH-(aq) (CH3)3C+(aq) + Cl·(aq) → (CH3)3CCl(aq) H(aq) + OH-(aq) → H₂O(1) E) (fast) (slow) C) (CH3)3COH(aq) + Cl·(aq) → (CH3)3CCl(aq) + OH-(aq) H+ (aq) + OH-(aq) → H₂O(1) D) (CH3)3COH(aq) + H+(aq) → (CH3)3C(OH₂) (aq) (CH3)3C(OH₂)(aq) → (CH3)3C¯(aq) + H₂O(1) (CH3)3C+ (aq) + Cl(aq) → (CH3)3CCl(aq) None of these mechanisms are consistent with the rate law provided. (slow) (fast) (slow) (fast) (fast) (fast) (slow) (fast)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

7. Tert-butyl alcohol reacts with aqueous hydrochloric acid to give tert-butyl chloride as
shown below:
(CH3)3COH(aq) + H¯(aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1)
For this reaction, rate = k[(CH3)3COH][H*]. With which mechanism is this rate law
consistent?
A) (CH3)3COH(aq) + H*(aq)
(CH3)3C(OH₂)*(aq)
B)
(CH3)3C(OH₂)*(aq) + Cl(aq) → (CH3)3CCl(aq) + H₂O(1)
(CH3)3COH(aq) → (CH3)3C+(aq) + OH-(aq)
(CH3)3C+ (aq) + Cl(aq) → (CH3)3CCl(aq)
H*(aq) + OH-(aq) → H₂O(1)
(CH3)3COH(aq) + Cl·‍(aq) → (CH3)3CCl*(aq) + OH¯(aq)
H*(aq) + OH-(aq) → H₂O(1)
(CH3)3COH(aq) + H*(aq) → (CH3)3C(OH₂)*(aq)
(CH3)3C(OH₂)*(aq) → (CH3)3C¯(aq) + H₂O(1)
(CH3)3C+(aq) + Cl(aq) → (CH3)3CCl(aq)
E) None of these mechanisms are consistent with the rate law provided.
C)
D)
(fast)
(slow)
(slow)
(fast)
(slow)
(fast)
(fast)
(fast)
(slow)
(fast)

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