Part A: Based on the energy diagram, determine which step is rate limiting. Answer: The first step Part B: What is the rate law of the reaction in part A? Part C: What is the order of the reaction based on the answer to part B?

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Chapter1: Chemical Foundations
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Part A: Based on the energy diagram, determine which step is rate limiting.

Answer: The first step

Part B: What is the rate law of the reaction in part A?

Part C: What is the order of the reaction based on the answer to part B? 

Consider the reaction in which HCl adds across the double bond of
ethene:
HCl + H2C = CH2→H3C – CH2C1
|
The following mechanism, with the following energy diagram shown
below, has been suggested for this reaction:
k1
HCl + H2C = CH2 = H3C – CH, + C1¯
k-1
k2
H3C – CH + CI¯ , H3C – CH2 Cl
- E2
-
Ea1
C=C + HCI
H-C-C-Cl
Reaction progress
->
Energy
Transcribed Image Text:Consider the reaction in which HCl adds across the double bond of ethene: HCl + H2C = CH2→H3C – CH2C1 | The following mechanism, with the following energy diagram shown below, has been suggested for this reaction: k1 HCl + H2C = CH2 = H3C – CH, + C1¯ k-1 k2 H3C – CH + CI¯ , H3C – CH2 Cl - E2 - Ea1 C=C + HCI H-C-C-Cl Reaction progress -> Energy
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