7. Draw a detailed mechanism for the H₂O initiated polymerization cyanoacrylate. Included the major chain termination reactions. Explain why the nitrile- and ester moieties are essential. What are the major applications of this family of polymers.
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- Draw the structure of the product of the Michael reaction between propenamide and diethyl malonateThis reaction does not follow the expected theory. Given what you know about substitution/elimination, what is the expected mechanism this reaction should follow? Suggest why that is not what happens and give the actual product of the reaction. Br ткон s1) Which type of polymerization will the molecule shown most readily undergo? a. Anionic b. Cationic C. Radical d. Ring-opening e. Will not polymerize
- i.) Ester hydrolysis can occur in acidic or basic conditions. Predict the product AND show the mechanism for the following addition/elimination reactions. Note that the first reaction is acid catalyzed and the second reaction is based catalyzed a.) " b.) مل NaOH H3O+ c.) Explain why an acid chloride reacts in neutral conditions to form the same product as 1 and 2 above. Show the mechanism for this hydrolysis reaction. WHY IS THIS REACTION NOT AN EQUILIBRIUM REACTION? CI H₂O* Question Completion Status: A Moving to the next question prevents changes to this answer. Question 2 Coupling a terminal alkyne with an alkenyl halide, using a mixture of a Pd and Cu(l) catalyst, is an example of O A. Sonogashira Coupling O B. Suzuki-Miyaura Coupling OC. Heck-Mizoroki Coupling OD. Gilman Reagent-Mediated Coupling O E. Stille Coupling and Carbonylation reaction A Moving to the next question prevents changes to this answer.The polymer shown below is synthesized by hydroxide ion-promoted hydrolysis of a copolymer of para-nitrophenyl methacrylate and acrylate. a. Propose a mechanism for the formation of the copolymer. b. Explain why hydrolysis of the copolymer to form the polymer occurs much more rapidly than hydrolysis of para-nitrophenyl acetate.
- 1. Write the general mechanism for a Nucleophilic Substitution Reaction.a) Free radical bromination is more selective than free radical chlorination. Draw a reaction coordinate diagram for the specific step in the radical chain mechanism that illustrates the source of this selectivity, and explain your reasoning. b) Explain why the bond dissociate energy (BDE) of tert-butane is 95 kcal/mol while the BDE for propane is 99 kcal/mol.Organic chemistry