6.1 Calculate the enthalpy of the reaction 2NO (g) + O2(g) -2NO2 (g), given the following reactions and enthalpies of formation: (i) 12 N₂ (g) + O₂-NO₂ (g) (ii) 12 N₂ (g) +120; (g) → NO(g) ΔΗ = 33.2 kJ ΔΗ = 90,2 kJ

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Question 6
6.1 Calculate the enthalpy of the reaction 2NO (g) + O2(g) →2NO2 (g), given the following
reactions and enthalpies of formation:
(i) 12 N₂ (g) + O₂-NO₂ (g)
(ii) 12 N₂(g) +120₂ (g) → NO(g)
ΔΗ = 33.2 kJ
ΔΗ = 90,2 kJ
6.2 The standard enthalpy of formation of NH3 (g) at 298 K is equal to -462.11 kJ mol'. Using
the heat capacity data given below (valid for the temperature range of 298 K to 1600 K).
Cp.m" (H₂) / J. K¹ mol¹ = 29.07- 0.837 x 103
+2.012 x 106
Cp, m. (N2) / J. K¹ mol¹ = 26.98 +5.192 x 103
-0.3376 x 1067
Cp. mº (NH3)/J.K¹ mol¹ = 25.89 +32.58 x 103-3.046 x 106
Calculate the standard molar heat of formation of NH3 (g) at 900 K (in kJ.mol'), at 1000 K. Give
your final answer to 3 significant figures.
Transcribed Image Text:Question 6 6.1 Calculate the enthalpy of the reaction 2NO (g) + O2(g) →2NO2 (g), given the following reactions and enthalpies of formation: (i) 12 N₂ (g) + O₂-NO₂ (g) (ii) 12 N₂(g) +120₂ (g) → NO(g) ΔΗ = 33.2 kJ ΔΗ = 90,2 kJ 6.2 The standard enthalpy of formation of NH3 (g) at 298 K is equal to -462.11 kJ mol'. Using the heat capacity data given below (valid for the temperature range of 298 K to 1600 K). Cp.m" (H₂) / J. K¹ mol¹ = 29.07- 0.837 x 103 +2.012 x 106 Cp, m. (N2) / J. K¹ mol¹ = 26.98 +5.192 x 103 -0.3376 x 1067 Cp. mº (NH3)/J.K¹ mol¹ = 25.89 +32.58 x 103-3.046 x 106 Calculate the standard molar heat of formation of NH3 (g) at 900 K (in kJ.mol'), at 1000 K. Give your final answer to 3 significant figures.
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