6. Rewrite figure 7.18 (Determining expected mechanisms) with relevant examples for box headers and example formechanisms in the boxes.Strong baseStrong baseWeak baseWeak baseWeak nucleophile Strong nucleophile Strong nucleophile Weak nucleophile1°E2E2SN2SN22°E2E2 SN2SN2XX3°E2E2SN1SN1 E1

"Determining expected mechanisms" with explanations for each box: Base StrengthNucleophile…

Answered: 6. Rewrite figure 7.18 (Determining…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter14: Elimination

Section: Chapter Questions

Problem 23E

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Label the nucleophile and the electrophile, the nucleophilic atom and the electrophilic atom.
You determine the bimolecular rate constant k for a set of SN2 reactions. Based on your understanding of how the nucleophile effects the rate constant for an SN2 reaction, drag and drop the nucleophiles into the correct rows in the table below. Alkyl halide Nucleophile k / L mol-1 s-1 CI 0.011 -CI 0.045 0.074 0.095 -NH2 -NH2 >-NH2 -NH2 -NH2
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A H2N. Figure 9: Multi-step reaction sequence
1c. What is the nucleophile in the following reaction? .Br CH;CO0 Na LO OCCH3 NaBr ld. What is the electrophile in the following reaction? Br CH;COO Na L0OCCH3 NaBr +
Analyze the Sn2 reactions by filling out the chart and answering the questions
1. Draw 2-methylpropanoic acid + thionyl chloride/pyridine catalysis + heat = ibuprofen intermediate C4H6OCI is the answer for the first intermediate (this one I already have it) 2. Draw ibuprofen intermediate 1 + benzene + AlCl3 + heat = ibuprofen intermediate 2. 3. Draw ibuprofen intermediate 2 + hydrazine = ibuprofen intermediate 3. 4. Draw ibuprofen intermediate 3 + KOH + heat = ibuprofen intermediate 4. 5. Draw ibuprofen intermediate 4 + ethanoyl chloride + AlCl3 + heat = ibuprofen intermediate 5. 6. Draw ibuprofen intermediate 5 + NaBH4 + hydronium workup = ibuprofen intermediate 6. (this one I have it already) 7. Draw ibuprofen intermediate 6 + HBr = ibuprofen intermediate 7. (this one i have it already)8. Draw ibuprofen intermediate 7 + Mg = ibuprofen intermediate 8. 9. Draw ibuprofen intermediate 8 + CO2 = ibuprofen intermediate 9. 10. this is the ibuprofen (i already have it)
Use the dropdown menu to indicate whether the rate of the reaction shown below will increase, decrease, or remain the same when the reaction conditions are changed to X or to Y or to Z (see below). NaCN Br CN CH3CN X: Change the leaving group from Br to CI Y: Increase the concentration of haloalkane Z: Increase the concentration of NaCN X: choose your answer... Y: choose your answer... Z: choose your answer... >
Which of the following does not support a nucleophilic attack of a covalent catalysis? a. Hydroxyl b. Sulfhydryl c. Imidazole d. Amino e. Methyl
Please answer BOTH questions, thanks so much!
Br CH3OH + Br-Br H3CO The mechanism proceeds through a first cationic intermediate, intermediate 1. Nucleophilic attack leads to intermediate 2, which goes on to form the final product. In cases that involve a negatively charged nucleophile, the attack of the nucleophile leads directly to the product. +Br + CH3OH Br Intermediate 1 Intermediate 2 (product) In a similar fashion, draw intermediate 1 and intermediate 2 (final product) for the following reaction. OH + Br2 + HBr Br racemic mixture • Pay attention to the reactants, they may differ from the examples. In some reactions, one part of the molecule acts as the nucleophile. • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate intermediate 1 and intermediate 2 using the → symbol from the dropdown menu.

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