5.2 A batch of poly(butylene terephthalate), PBT, is made by reacting butylene glycol (also known as 1,4-butane diol) with terephthalic acid, see example 2.4C. A total of 5 moles of polymer is made. The mixture contains 1.06 moles with a molecular weight of 207,900, 0.65 moles with a molecular weight of 210,100, 0.54 moles with a molecular weight of 211,420, 1.13 moles with a molecular weight of 212,080, 0.77 moles with a molecular weight of 215,160, and 0.85 moles with a molecular weight of 480,920. (Note: the above means that there are 1.06 moles of chains that have the same degree of polymerization to give the MW of 207,900, and similar for each of the other entries)

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5.2 A batch of poly(butylene terephthalate), PBT, is made by reacting butylene glycol (also known as
1,4-butane diol) with terephthalic acid, see example 2.4C. A total of 5 moles of polymer is made. The mixture
contains 1.06 moles with a molecular weight of 207,900, 0.65 moles with a molecular weight of 210,100, 0.54
moles with a molecular weight of 211,420, 1.13 moles with a molecular weight of 212,080, 0.77 moles with a
molecular weight of 215,160, and 0.85 moles with a molecular weight of 480,920.
(Note: the above means that there are 1.06 moles of chains that have the same degree of
polymerization to give the MW of 207,900, and similar for each of the other entries)
Transcribed Image Text:5.2 A batch of poly(butylene terephthalate), PBT, is made by reacting butylene glycol (also known as 1,4-butane diol) with terephthalic acid, see example 2.4C. A total of 5 moles of polymer is made. The mixture contains 1.06 moles with a molecular weight of 207,900, 0.65 moles with a molecular weight of 210,100, 0.54 moles with a molecular weight of 211,420, 1.13 moles with a molecular weight of 212,080, 0.77 moles with a molecular weight of 215,160, and 0.85 moles with a molecular weight of 480,920. (Note: the above means that there are 1.06 moles of chains that have the same degree of polymerization to give the MW of 207,900, and similar for each of the other entries)
A. What are the molecular weights of each of the monomers used to make PBT?
B. What is the molecular weight of the repeat unit PBT?
C. What is the number-average molecular weight of the PBT sample?
D. What is the number-average degree of polymerization of the PBT sample?
E. What is the weight-average molecular weight of the PBT sample?
F. What is the z-average molecular weight of the PBT sample?
G. What is the polydispersity index of this sample?
H. List two different products that are commonly made of PBT (use the internet).
Transcribed Image Text:A. What are the molecular weights of each of the monomers used to make PBT? B. What is the molecular weight of the repeat unit PBT? C. What is the number-average molecular weight of the PBT sample? D. What is the number-average degree of polymerization of the PBT sample? E. What is the weight-average molecular weight of the PBT sample? F. What is the z-average molecular weight of the PBT sample? G. What is the polydispersity index of this sample? H. List two different products that are commonly made of PBT (use the internet).
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