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5. Provide a detailed, stepwise mechanism for the reaction of acetyl chloride with n- propylamine.

5. Provide a detailed, stepwise mechanism for the reaction of acetyl chloride with n- propylamine.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Thorough explanations please. Appreciated.

5. Provide a detailed, stepwise mechanism for the reaction of acetyl chloride with n- propylamine. 6. Which would be more appropriate as the reduction in the following sequence, a Clemmensen or a Wolff-Kishner? Explain. CHO 1. HOCH₂CH₂OH (1 eq), H 2. reduction 3. H30* www. 7. Which has the higher boiling point, 1-butanol or 1-butanamine? or CHO 8. Circle the stronger base in the pair below, and briefly explain your choice. (CH3CH2)2NH 9. How might one distinguish a sample of trimethylamine from a sample of n-propylamine using IR spectroscopy? ¹H NMR spectroscopy? ¹3C NMR spectroscopy?
Transcribed Image Text:5. Provide a detailed, stepwise mechanism for the reaction of acetyl chloride with n- propylamine. 6. Which would be more appropriate as the reduction in the following sequence, a Clemmensen or a Wolff-Kishner? Explain. CHO 1. HOCH₂CH₂OH (1 eq), H 2. reduction 3. H30* www. 7. Which has the higher boiling point, 1-butanol or 1-butanamine? or CHO 8. Circle the stronger base in the pair below, and briefly explain your choice. (CH3CH2)2NH 9. How might one distinguish a sample of trimethylamine from a sample of n-propylamine using IR spectroscopy? ¹H NMR spectroscopy? ¹3C NMR spectroscopy?
1. The following structure has been used in monitoring the development of amyloid plaques in Alzheimer's patients (J. Med. Chem. 2011, 949). Rank the numbered N atoms in order of increasing pKb value? 2. Provide the structure of the major organic product in the reaction below. Mechanism? CHO H3CO + CH3NH₂ of H catalyst 3. Predict the major organic product of the following reaction: 1. HNO3, H₂SO4 2. H₂, Ni 4. Draw the structure of N,N-dimethyl-1-hexanamine. What would be the common name?
Transcribed Image Text:1. The following structure has been used in monitoring the development of amyloid plaques in Alzheimer's patients (J. Med. Chem. 2011, 949). Rank the numbered N atoms in order of increasing pKb value? 2. Provide the structure of the major organic product in the reaction below. Mechanism? CHO H3CO + CH3NH₂ of H catalyst 3. Predict the major organic product of the following reaction: 1. HNO3, H₂SO4 2. H₂, Ni 4. Draw the structure of N,N-dimethyl-1-hexanamine. What would be the common name?
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