5) Acetylsalicylic acid (HC,H;O4) is a monoprotic acid commonly known as "aspirin". A typical aspirin tablet, however, contains only a small amount of the acid. In an experiment to determine its composition, an aspirin tablet was crushed and dissolved in water. It took 12.25 mL of 0.1466 M NaOH to neutralize the solution. Calculate the number of grains of aspirin in the tablet (one grain 0.0648 g). (assume acid:base ratio is 1:1).

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**Challenge Problems**

1) A 25.00 mL sample of unknown concentration of HNO₃ solution requires 22.62 mL of 0.02000 M NaOH to reach the equivalence point. What is the concentration of the unknown HNO₃ solution?

2) A 15.0 mL sample of 1.78 x 10⁻³ M Ca(OH)₂ is being titrated against 2.18 x 10⁻³ M HCl. Determine the volume of HCl needed to reach the equivalence point.

3) A 30.00 mL sample of unknown concentration of H₃PO₄ solution is titrated with 0.100 M Ba(OH)₂ solution. The equivalence point is reached when 26.38 mL of Ba(OH)₂ solution is added. What is the concentration of the unknown H₃PO₄ solution?

4) A 35.0 mL sample of 1.78 x 10⁻² M H₂C₂O₄ is being titrated against 2.18 x 10⁻² M HBr. Determine the volume of HBr needed to reach the equivalence point.

5) Acetylsalicylic acid (HC₉H₇O₄) is a monoprotic acid commonly known as "aspirin". A typical aspirin tablet, however, contains only a small amount of the acid. In an experiment to determine its composition, an aspirin tablet was crushed and dissolved in water. It took 12.25 mL of 0.1466 M NaOH to neutralize the solution. Calculate the number of grains of aspirin in the tablet (one grain = 0.0648 g). (assume acid:base ratio is 1:1).
Transcribed Image Text:**Challenge Problems** 1) A 25.00 mL sample of unknown concentration of HNO₃ solution requires 22.62 mL of 0.02000 M NaOH to reach the equivalence point. What is the concentration of the unknown HNO₃ solution? 2) A 15.0 mL sample of 1.78 x 10⁻³ M Ca(OH)₂ is being titrated against 2.18 x 10⁻³ M HCl. Determine the volume of HCl needed to reach the equivalence point. 3) A 30.00 mL sample of unknown concentration of H₃PO₄ solution is titrated with 0.100 M Ba(OH)₂ solution. The equivalence point is reached when 26.38 mL of Ba(OH)₂ solution is added. What is the concentration of the unknown H₃PO₄ solution? 4) A 35.0 mL sample of 1.78 x 10⁻² M H₂C₂O₄ is being titrated against 2.18 x 10⁻² M HBr. Determine the volume of HBr needed to reach the equivalence point. 5) Acetylsalicylic acid (HC₉H₇O₄) is a monoprotic acid commonly known as "aspirin". A typical aspirin tablet, however, contains only a small amount of the acid. In an experiment to determine its composition, an aspirin tablet was crushed and dissolved in water. It took 12.25 mL of 0.1466 M NaOH to neutralize the solution. Calculate the number of grains of aspirin in the tablet (one grain = 0.0648 g). (assume acid:base ratio is 1:1).
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