4. You mix 50.0 mL of a weak monoprotic acid with 50.0 mL of NaOH solution in a coffee cup calorimeter. Both solutions (and the calorimeter) were initially at 22.0°C. The final temperature of the neutralization reaction was determined to be 22.5°C. a) What is the total amount of heat evolved in this reaction? Show all work. b) If 0.135 moles of the monoprotic acid were neutralized in this reaction, what is the molar heat of neutralization (enthalpy) for this reaction?

4. You mix 50.0 mL of a weak monoprotic acid with 50.0 mL of NaOH solution in a coffee cup calorimeter. Both solutions (and the calorimeter) were initially at 22.0°C. The final temperature of the neutralization reaction was determined to be 22.5°C. a) What is the total amount of heat evolved in this reaction? Show all work. b) If 0.135 moles of the monoprotic acid were neutralized in this reaction, what is the molar heat of neutralization (enthalpy) for this reaction?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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ch.10.
Simple Calorimetry. A piece of solid aluminum at 15.0°C is immersed in 12.3 g of nitrogen gas which is initially at 51.1°C and the system is allowed to equilibrate. Given that the specific heat of solid aluminum is 0.908 J/K/g and the specific heat of nitrogen gas is 1.0 J/K/g, what is the mass of the piece of solid aluminum if the final temperature is 34.7°C?
A chemist measures the energy change AH during the following reaction: Cl₂(g) + H₂(g) → 2 HCl(g) Use the information to answer the following questions. This reaction is... Suppose 14.7 of Cl₂ react. g Will any heat be released or absorbed? ΔΗ = - 184. kJ If you said heat will be released or absorbed in the second part of this question, calculate how much heat will be released or absorbed. Round your answer to 3 significant digits. endothermic. O exothermic. O Yes, absorbed. Yes, released. O No. ០៤ kJ ☐x10 X
In a coffee cup calorimeter, 50.0 mL of 1.00 M NaOH and 50.00 mL of 1.00 M HCl are mixed. Both solutions were originally at 24.6 C. After the reaction, the final temperature is 31.3 C. Given that the density of NaCl solution is 1.038 g/mL and the specific heat of NaCl solution is 3.87, calculate the change in enthalpy of neutralization per mole for the reaction of HCl with NaOH. Assume that no heat is lost to the surroundings.
For an exothermic reaction, how is the measured temperature change affected if some of the heat produced transfers to the calorimeter? How will the determination of the specific heat of the metal be affected if the thermometer used to record the temperature of the water bath reads too low?
4. The reaction of 250.0 mL of a 1.00 M hydrochloric acid solution with 250.0 mL of a 1.00 M sodium hydroxide solution was carried out in a constant pressure calorimeter. The total heat capacity of the calorimeter plus solutions was 6.45 kJ/K. The temperature of the calorimeter and solutions increased by 2.11°C. What is AH (in kJ) for the neutralization of 1.00 mol HCl(aq) by NaOH(aq)? A) -54.4 B) -21.2 +12.6 +54.4 E) -12.6
A 30.0 g sample of chromium is heated to 100.0 °C in a boiling water bath. The sample is added to a calorimeter charged with 45.0 mL of water at 34.1 °C. The final temperature of the calorimeter contents is 38.5 °C. Calculate the specific heat of chromium.
To measure the enthalpy of an acid-base reaction, a student places the thermometer in the hydrochloric acid solution, and then, without rinsing with DI water, places it in the sodium hydroxide solution prior to adding the hydrochloric acid solution to the calorimeter. How would this affect the calculated enthalpy of the reaction, be too high, too low, or unaffected? Why?
6, A 0.213 g sample of an organic compound with a molar mass of 386.0 g/mol was burned in the bomb calorimeter with a heat capacity of 2.54 kJ/K. The temperature in the calorimeter increased by 4.12 K. Calculate the energy of combustion of the compound in kJ/mol. A, –1.896 x103 B, –4.90 x102 C, 0.00937 D, –1.90 x104 E, -531
4. Consider a 15.0 g piece of tin metal initially at 25 oC, What is its specific heat if adding 250 cal to it causes its temperature to increase to 125 oC.