4. The following reaction scheme shows the radical polymerization of styrene to make polystyrene. a) Add electron-pushing arrows to show the mechanisms of steps 1-3. Determine if these are init propagation, or termination steps. b) Radical polymerization is often performed in the absence of O2 because the oxygen radical can coupl the polymer radical to terminate polymerization. Propose electron-pushing arrows for step 4 and pred product of that step. hv
4. The following reaction scheme shows the radical polymerization of styrene to make polystyrene. a) Add electron-pushing arrows to show the mechanisms of steps 1-3. Determine if these are init propagation, or termination steps. b) Radical polymerization is often performed in the absence of O2 because the oxygen radical can coupl the polymer radical to terminate polymerization. Propose electron-pushing arrows for step 4 and pred product of that step. hv
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:4. The following reaction scheme shows the radical polymerization of styrene to make polystyrene.
a) Add electron-pushing arrows to show the mechanisms of steps 1-3. Determine if these are initiation,
propagation, or termination steps.
b) Radical polymerization is often performed in the absence of O2 because the oxygen radical can couple with
the polymer radical to terminate polymerization. Propose electron-pushing arrows for step 4 and predict the
product of that step.
1
hv
3
BzO
Bzof
*0-0°
step 3 keeps happening
until a termination step
4
OCcurs
2.
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