For an alkene to polymerize easily via cationic polymerization... A) Atoms adjacent to the carbocation should have 8- B) Atoms adjacent to the carbocation should have &+ C) Atoms adjacent to the carboanion should have 8- D) Atoms adjacent to the carboanion should have &+

Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
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Chapter22: Substituted Hydrocarbons And Their Reactions
Section22.5: Polymers
Problem 22SSC
Question
### Understanding Cationic Polymerization for Alkenes

To facilitate the polymerization of an alkene via cationic polymerization, consider the following conditions regarding the atoms adjacent to the reactive intermediates:

A) **Atoms adjacent to the carbocation should have δ-**
   - This condition implies that the neighboring atoms should have a slight negative charge to stabilize the positive charge on the carbocation by electron donation.

B) **Atoms adjacent to the carbocation should have δ+**
   - This option suggests that the adjacent atoms should have a slight positive charge, which is less favorable as it would destabilize the carbocation by electron withdrawal.

C) **Atoms adjacent to the carbanion should have δ-**
   - For carbanions, nearby atoms with a slight negative charge would destabilize the negative charge on the carbanion.

D) **Atoms adjacent to the carbanion should have δ+**
   - This suggests that atoms near the carbanion should have a slight positive charge, stabilizing the carbanion by attracting electrons.

This information is crucial for understanding how various charges influence the stability of reactive intermediates in polymerization processes.
Transcribed Image Text:### Understanding Cationic Polymerization for Alkenes To facilitate the polymerization of an alkene via cationic polymerization, consider the following conditions regarding the atoms adjacent to the reactive intermediates: A) **Atoms adjacent to the carbocation should have δ-** - This condition implies that the neighboring atoms should have a slight negative charge to stabilize the positive charge on the carbocation by electron donation. B) **Atoms adjacent to the carbocation should have δ+** - This option suggests that the adjacent atoms should have a slight positive charge, which is less favorable as it would destabilize the carbocation by electron withdrawal. C) **Atoms adjacent to the carbanion should have δ-** - For carbanions, nearby atoms with a slight negative charge would destabilize the negative charge on the carbanion. D) **Atoms adjacent to the carbanion should have δ+** - This suggests that atoms near the carbanion should have a slight positive charge, stabilizing the carbanion by attracting electrons. This information is crucial for understanding how various charges influence the stability of reactive intermediates in polymerization processes.
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