For an alkene to polymerize easily via cationic polymerization... A) Atoms adjacent to the carbocation should have 8- B) Atoms adjacent to the carbocation should have &+ C) Atoms adjacent to the carboanion should have 8- D) Atoms adjacent to the carboanion should have &+
For an alkene to polymerize easily via cationic polymerization... A) Atoms adjacent to the carbocation should have 8- B) Atoms adjacent to the carbocation should have &+ C) Atoms adjacent to the carboanion should have 8- D) Atoms adjacent to the carboanion should have &+
Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter22: Substituted Hydrocarbons And Their Reactions
Section22.5: Polymers
Problem 22SSC
Related questions
Concept explainers
Question

Transcribed Image Text:### Understanding Cationic Polymerization for Alkenes
To facilitate the polymerization of an alkene via cationic polymerization, consider the following conditions regarding the atoms adjacent to the reactive intermediates:
A) **Atoms adjacent to the carbocation should have δ-**
- This condition implies that the neighboring atoms should have a slight negative charge to stabilize the positive charge on the carbocation by electron donation.
B) **Atoms adjacent to the carbocation should have δ+**
- This option suggests that the adjacent atoms should have a slight positive charge, which is less favorable as it would destabilize the carbocation by electron withdrawal.
C) **Atoms adjacent to the carbanion should have δ-**
- For carbanions, nearby atoms with a slight negative charge would destabilize the negative charge on the carbanion.
D) **Atoms adjacent to the carbanion should have δ+**
- This suggests that atoms near the carbanion should have a slight positive charge, stabilizing the carbanion by attracting electrons.
This information is crucial for understanding how various charges influence the stability of reactive intermediates in polymerization processes.
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry: Matter and Change
Chemistry
ISBN:
9780078746376
Author:
Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:
Glencoe/McGraw-Hill School Pub Co

Chemistry for Today: General, Organic, and Bioche…
Chemistry
ISBN:
9781305960060
Author:
Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:
Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:
9780078746376
Author:
Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:
Glencoe/McGraw-Hill School Pub Co

Chemistry for Today: General, Organic, and Bioche…
Chemistry
ISBN:
9781305960060
Author:
Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:
Cengage Learning

Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning

Introductory Chemistry: An Active Learning Approa…
Chemistry
ISBN:
9781305079250
Author:
Mark S. Cracolice, Ed Peters
Publisher:
Cengage Learning

Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:
9780618974122
Author:
Andrei Straumanis
Publisher:
Cengage Learning