4. Predict whether each of the following substitution reactions is likely to be SN 1or SN2. CI OAC CH3CO2¯ Na* CH3CO2H, H2O а. CH2Br CH2OAC CH3CO2- Na* DMF b. HO. HCI CI CH3OH с. CH3 CH3 Na+ SCH3 H2C=CCH2SCH3 H2C=CCH2BR d. CH3CN 5. Setting aside the double bond stereochemistry, what products would you expect from elimination reactions of the following alkyl halides? CH3 CI CH3 CH3CHCH2-C–CHCH3 ČH3 6. From what alkyl halides are the following alkenes have been made? CH3 CH3 CH3CHCH2CH2CHCH=CH2

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

please i really need help to answer all of them :(( even without explanation

4. Predict whether each of the following substitution reactions is likely to be SN 1or SN2.
CI
OAC
CH3CO2¯ Na*
CH3CO2H, H2O
а.
CH2Br
CH2OAC
CH3CO2- Na*
DMF
b.
HO.
HCI
CI
CH3OH
с.
CH3
CH3
Na+ SCH3
H2C=CCH2SCH3
H2C=CCH2BR
d.
CH3CN
5. Setting aside the double bond stereochemistry, what products would you expect from
elimination reactions of the following alkyl halides?
CH3
CI CH3
CH3CHCH2-C-CHCH3
CH3
6. From what alkyl halides are the following alkenes have been made?
CH3
CH3
CH3CHCH2CH2ČHCH=CH2
7. Which of the two isomers would you expect to undergo E2 elimination faster? trans-1-bromo-
4-tert-butylcyclohexane or cis-1-bromo-4-tert-butylcyclohexane? Draw each molecule in its
more stable chair conformation. Provide an explanation to your answer.
Transcribed Image Text:4. Predict whether each of the following substitution reactions is likely to be SN 1or SN2. CI OAC CH3CO2¯ Na* CH3CO2H, H2O а. CH2Br CH2OAC CH3CO2- Na* DMF b. HO. HCI CI CH3OH с. CH3 CH3 Na+ SCH3 H2C=CCH2SCH3 H2C=CCH2BR d. CH3CN 5. Setting aside the double bond stereochemistry, what products would you expect from elimination reactions of the following alkyl halides? CH3 CI CH3 CH3CHCH2-C-CHCH3 CH3 6. From what alkyl halides are the following alkenes have been made? CH3 CH3 CH3CHCH2CH2ČHCH=CH2 7. Which of the two isomers would you expect to undergo E2 elimination faster? trans-1-bromo- 4-tert-butylcyclohexane or cis-1-bromo-4-tert-butylcyclohexane? Draw each molecule in its more stable chair conformation. Provide an explanation to your answer.
Expert Solution
steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Electronic Effects
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY