Answered: (4) Determine the point group of CHa…

(4) Determine the point group of CHa and show the symmetry elements/operations using 3D drawing. (5) Determine the point group of SF6 and show the symmetry elements/operations using 3D drawing.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.25E: Point groups are called such because all of the symmetry elements in the group intersect at one...

See similar textbooks

Related questions

Q: The point group C2y has four operations: E, C2, 0y and oy. Taking water as an example for the point…

A: σV' operation is the equivalent

Q: what is the point group of BeF3-

Q: Determine the point groups of the following molecule: XeF4

A: A point group express all the symmetry operations that can be execute on a molecule that result in a…

Q: For each of the following molecules, list the symmetry elements present and assign its point group.…

A: The symmetry elements and point group for a, b & c = ? Note : As per our company guidelines :…

Q: XeF4 has a molecular geometry of square planar. i. How would you determine its point group? ii.…

A: XeF4 has planar geometry in which Xe present at the cut point of two diagonals of the square and 4…

Q: - Determine the irreducible representations with reasons in the following character table. CE IR. R,…

A: When E=1 ,then one dimensional, representation may A or B If it is symmetric about principal axis…

Q: The above drawing represents a SALC made up of H1s orbitals for the molecule ethene. This molecule…

A: To identify the irreducible representation for the Given SALC of ethene which belongs to the D2h…

Q: 1) The molecule CIF; belongs to the point group shown below: C4v E 2C4 C2 20, 20a A1 1 1 1 A2 1 1 1…

A: Cl atom in the centre of Cartesian coordinate, with C4 axis pass through z axis as it is a principle…

Q: Identify the point group of CCI,. O C2v O Cav C4h O Ta O D4h

A: Td group For Td group, symmetry elements are E, 3C2, 4C3, 3S4 and 6σd. And symmetry operations are…

Q: Assign (i) cis-dichloroethene and (ii) trans-dichloroethene to point groups.

A: Before assigning the point group determine the symmetry operations which are operative in the…

Q: (iii) List and depict all the symmetry elements and deduce the point group. ÇI Co.CO CO

Q: Make sketches of the following showing approximately correct geometry and all valence shell…

A: “Since you have posted a question with multiple sub-parts, we will solve the first three subparts…

Q: Show that the function x y z has symmetry species A1 in pt group D2,

A: i) E : E operation does not change the function xyz, i.e., E xyz = xyz hence corresponding…

Q: Determine the point group of each molecule. Show the different symmetry elements. 5.S0₂

Q: (b) Decompose the representation below into the irreducible representations of C3v. 2C3 1 C3v T E…

A: An irreducible representation of a group is a group representation that has no nontrivial invariant…

Q: Write the transformation matrices for all the symmetry elements present in the C2v point group

A: Group Theory is a mathematical method by which molecules symmetry and their symmetry operations can…

Q: Make sketches of the following showing approximately correct geometry and all valence shell…

Q: Write all symmetry elements and point group of PCI5 molecule. (Draw the shape

A: Write all symmetry elements and point group of PCI5 molecule ?

Q: A point group has the following sets of elements E, 8 C3, 3C2, 6 S4, 6 od. The order and number of…

A: We know tetrahedral point group has E, 8 C3 , 3 C2 , 6 S4 and 6 σd. Where the numbers before…

Q: Determine the point group of the following ions/molecules: a) 1,3-bromochlorobenzene b)…

Q: point groups and symmetry elements

Q: Consider the molecule allene, where the middle carbon is located on the origin and the z- axis…

A: Allene: Allene is arrangement of carbon having carbon which is double bonded to both adjacent…

Q: 1. Determine the symmetry elements present in each molecule below, then identify the point group…

Q: Consider the octahedral molecule [ML6]: 1) Draw the structure and show all axes 2) Write down all…

Q: What is the point group of NOCl? a. C∞v b. Cs c. none of the above is a correct point group d.…

A: Point group: In group theory, the point group represent all the symmetry element and the symmetry…

Q: A scrambled character table for a polyhedral point group is shown here, though missing a couple of…

A: To predict the (a) order of a polyhedral point group. (b) number of classes for a polyhedral point…

Q: How many classes are there in Dsa point group, write them. Write one subgroup of this point group.

A: For a Dsa group, ie, D3h group, total no. Of different symmetry operations of a molecule is given by…

Q: Explain what is meant by irreducible representations, non-degenerate representations and degenerate…

A: Point groups are identified using the set of symmetry elements each of them possess and are used to…

Q: Find/show all possible symmetry operations and the point group of the following compounds by drawing…

A: The objective of the question is to show all possible symmetry operations and the point groups of…

Q: 4 Considering the carbonate atomic (CO32- ) construct the SALCS. 1) Make a table that has each…

A: Solution- the carbonate atomic (CO32- ) construct the SALCS. 1) We have to make a table that has…

Q: All mirror plane of HOCI, PTCI2B12 and the other symmetry elements Or Determination of the point…

A: HOCl doesn't contain mirror plane. PtCl2Br2 contain mirror plane CCl4 point group- Td. BCl3 point…

Q: Determine the character of the representation developed when something of E’’ symmetry is combined…

A: Combining E'' and E' in D3hThe character table of the D3h point group is essential to determining…

Q: Pick 2 of the molecules below. For the two of your choice, draw the structure, identify the symmetry…

Q: Determine the point group of the pattern on the flag of Japan.

A: SYMMETRY OPERATIONS: In quantum chemistry, a symmetry operation is conducted by a geometrical…

Q: Draw the shape of the [XEFS] ion and answer the questions below: (i) List the symmetry elements and…

Q: 2) Use the C2 point group to illustrate that the irreducible representations in a character table…

A: The character table for the C2 point group is shown below.

Q: List the symmetry elements of the following molecules and name the point groups to which they…

A: Symmetry Elements : Symmetry elements are mathematical tools which are used to analyze the geometry…

Question

(4) Determine the point group of CHa and show the symmetry elements/operations using 3D drawing.
(5) Determine the point group of SF6 and show the symmetry elements/operations using 3D drawing.

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

In your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.
Determine the point group of the following molecules. a cis1,2 Dichloroethylene b trans1,2 Dichloroethylene c Toluene, C6H5CH3 d 1,3-Cyclohexadiene.
Determine which single symmetry operation of the following point groups is equivalent to the given combination of multiple symmetry operations. a In C2v, C2v=? b In C2h, iC2=? c In D6h, C6h=? d In D2d, C2C2=? e In Oh, iS4=?
Why is it unnecessary to consider whether an irreducible representation from C4h is orthogonal to an irreducible representation of D6h?
Show that any two of the irreducible representations of the following point groups are orthogonal to each other. a C2 b C2v c D2h d Oh e Td
a In the Td point group, an S41 improper rotation is equivalent to what other improper rotation? b In the D6h point group, the symmetry operation labeled C21 is equivalent to what other symmetry operation?
Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.
Identify the point group of the wave functions of the following molecules. a Hydrogen chloride, HCl b Sulfur dioxide, SO2 c Sulfur trioxide, SO3
Linearly polarized light can be assigned a specific irreducible representation of a symmetry point group. If the electronic ground state of methane has A1g symmetry and x- polarized light has the label T2, what are the symmetry labels of allowed excited electronic states? Use the Td character table in Appendix 3.
Determine the symmetry species of the D3h point group for the sp2 hybrid orbitals, assuming that the C3 axis is coincident with the z-axis and that one of the orbitals lies along the positive x-axis. See Example 13.16.
Identify the symmetry elements present in the following objects. a The Eiffel Tower. You may have to look up a picture of it if you dont remember its shape b Any book ignore the printing. c An octagonal wood block. d A jack from the set of jacks pictured here: Note that some of the points end differently.
Figure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine. Determine the symmetry elements present in the molecule, and its point group. Does the point group change if an Fe2+ ion is substituted for the two hydrogen atoms in the center of the porphine ring?