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1) The molecule CIF; belongs to the point group shown below: C4v E 2C4 C2 20, 20a A1 1 1 1 A2 1 1 1 -1 -1 B1 -1 1 1 -1 B2 1 -1 1 -1 1 2 0 -2 0 (x, y) E a) Draw CIF; using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dỵy and a ii) d,2 orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for

1) The molecule CIF; belongs to the point group shown below: C4v E 2C4 C2 20, 20a A1 1 1 1 A2 1 1 1 -1 -1 B1 -1 1 1 -1 B2 1 -1 1 -1 1 2 0 -2 0 (x, y) E a) Draw CIF; using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dỵy and a ii) d,2 orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1) The molecule CIF; belongs to the point group shown below: E 2C4 C2 20, 20d A1 1 1 1 1 z A2 1 1 1 -1 -1 B1 1 -1 1 1 -1 B2 1 -1 1 -1 1 E 0 (x, y) -2 a) Draw CIF; using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dxy and a ii) d,2 orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCS with that symmetry. Example: If this question were asking about the composition of the MOs of water (C2, point group), your answer would include the following - a1: 2s (oxygen), H2 SALC, and 2p, (oxygen)
Transcribed Image Text:1) The molecule CIF; belongs to the point group shown below: E 2C4 C2 20, 20d A1 1 1 1 1 z A2 1 1 1 -1 -1 B1 1 -1 1 1 -1 B2 1 -1 1 -1 1 E 0 (x, y) -2 a) Draw CIF; using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dxy and a ii) d,2 orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCS with that symmetry. Example: If this question were asking about the composition of the MOs of water (C2, point group), your answer would include the following - a1: 2s (oxygen), H2 SALC, and 2p, (oxygen)
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