Draw the shape of the [XeFs] ion and answer the questions below:(i)List the symmetry elements and the symmetry operations of the [XEF5] ion.(ii)What is the point group of the [XeF5] ion? What is the order of the point group of the[XeFs] ion?(iii) Using the [XeF5] as an example, show that C" = E.

Answered: Image /qna-images/answer/e82a2877-e3df-4132-9ade-918e9a8597d6.jpg

Draw the shape of the [XEFS] ion and answer the questions below: (i) List the symmetry elements and the symmetry operations of the [XeFs] ion. (ii) What is the point group of the [XeF5] ion? What is the order of the point group of the [XeFs] ion? (iii) Using the [XeF5] as an example, show that C" = E.

Draw the shape of the [XEFS] ion and answer the questions below: (i) List the symmetry elements and the symmetry operations of the [XeFs] ion. (ii) What is the point group of the [XeF5] ion? What is the order of the point group of the [XeFs] ion? (iii) Using the [XeF5] as an example, show that C" = E.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Determine the point group of each of the following molecules or ions, whose shapes can be determined by use of valence-shell electron-pair repulsion. (VSEPR) theory: (a) SeF5. (b) CIF, (c) ASF, (d) XeF₂, (e) XeF4. (f) BeF3. (g) SiF2, (h) OCN, (i) ASCI, (j) OSF4, (k) trans-FNNF, (1) cis-FNNF, (m) CISSCI (nonplanar), (n) S₂O3, (o) trans-(OH)4XeO₂. ww Identify the point group for each of the following Fe³+ complexes with the biden- tate oxalate ligand (ox = C₂O2). Where allowed by the point group, determine which complexes are chiral. [Hint: Use models to help identify the point group and to verify the existence of enantiomers.] (a) tris(oxalato)ferrate(III), [Fe(ox);]³ (b) trans-dichlorobis(oxalato)ferrate(III). [FeCl₂(ox)₂³ (c) cis-dichlorobis(oxalato)ferrate(III), [FeCl₂(ox)₂] (d) cis-dibromo-trans-dichlorooxalatoferrate (III). [FeBr₂Cl₂ox]³ (e) cis-dibromodichlorooxalatoferrate(III), [FeBr₂Cl₂ox]³.
QUESTION 2 (i) What is the basis of C versus D point group classification? (ii) Draw a pz and a d orbital and assign their point groups.
(a) Complete the following table: Molecule/lon Geometry of molecule Key symmetry elements Point group B(F)(CI)(Br) [S203]²
Give all the symmetry elements in the following molecules, and assign the point group of each. a ) Xe(0) F4 b) cyclo-(C5H5) - c) IF 7 (pentagonal bipyramidal) d) Boric acid (right - assume it's rigid)
(4) Determine the point group of CHa and show the symmetry elements/operations using 3D drawing. (5) Determine the point group of SF6 and show the symmetry elements/operations using 3D drawing.
The structure of [NO3]-is either trigonal planar or trigonal pyramidal draw both possible structures and determine the point group for each. Which irreducible representations represent the translational and rotational modes for each possible structure of [NO3]-? Which irreducible representations correspond to the vibrational modes for each possible structure of [NO3]-? How many degrees of freedom would you expect for each structure of [NO3]-? Calculate T-vibrationaland determine which modes you expect to be IR active for each structure.
(b) Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO-]²" ion have: (i) C4 (ii) ơh (iii) S4.
Subject: chemistry
Using the relationships imposed by the orthogonality theorem, predict the characters, XK(R), that have been omitted from this table, and match each with its correct value. All symmetry elements and irreducible representations (labelled with subscripts k = 1, 2, 3, 4, and 5) are included in this table. + X2(C3) ◆ X3(C₂) + X4(0d) X5(E) - ₁₁ [₂ [3 T4 [5 E 1 3 1 3 _?___ 6 S4 8 C3 1 1 1 -1 T -1 0 ? 1 0 -1 A. 1 B.-2 C. 2 D.-1 E. 3 F. 0 3 C₂ 1 -1 ? 어 -1 2 60d 1 -1 -1 ? O
list the symmetry operations and determine the point group for each molecule.
(c) Using POC13 as an example, develop the reducible representation of its point group.
Consider the octahedral species CrCl63- (point group Oh). What point group results by removing one Cl replacing one Cl with one Br removing two trans Cl’s removing two cis Cl’s removing three mutually adjacent Cl’s.