A. L.. 5 2 3 Consider the trimethylenecyclopropane molecule (point group D3h). Each carbon atom has a pz orbital to contribute to the pi- MOs of the molecule. Take these 6 pz orbitals as a basis set and answer the following questions: A) How do they divide into subsets of symmetry - equivalent orbitals? R) What representations are

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter13: Introduction To Symmetry In Quantum Mechanics
Section: Chapter Questions
Problem 13.82E: Determine the symmetry species of the D3h point group for the sp2 hybrid orbitals, assuming that the...
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Å L.
Y
→ X
5
3
Consider the
trimethylenecyclopropane molecule
(point group D3h). Each carbon atom
has a pz orbital to contribute to the pi-
MOs of the molecule. Take these 6 pz
orbitais as a basis set and answer the
following questions:
A) How do they divide into subsets
of symmetry - equivalent orbitals?
B) What representations are
spanned by each subset?
C) What are the 6 normalized
Transcribed Image Text:Å L. Y → X 5 3 Consider the trimethylenecyclopropane molecule (point group D3h). Each carbon atom has a pz orbital to contribute to the pi- MOs of the molecule. Take these 6 pz orbitais as a basis set and answer the following questions: A) How do they divide into subsets of symmetry - equivalent orbitals? B) What representations are spanned by each subset? C) What are the 6 normalized
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