3. Given that a mixture of methanol and carbon tetrachloride forms a minimum-boiling- point azeotrope that boils at 55.7 °C with a composition of 20% methanol to 80% carbon tetrachloride: a. Construct an approximate boiling-point-phase diagram (with % composition on the x-axis and temperature on the y-axis) for this system. Include the boiling points of pure methanol, pure carbon tetrachloride, and the boiling point of the azeotrope on your diagram. b. Describe the behavior on distillation of a mixture that is 90% methanol and 10% carbon tetrachloride.

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21,743
FEB
22
3.
4.
5.
h (page 2 of 2)
Given that a mixture of methanol and carbon tetrachloride forms a minimum-boiling-
point azeotrope that boils at 55.7 °C with a composition of 20% methanol to 80%
carbon tetrachloride:
a. Construct an approximate boiling-point-phase diagram (with % composition on
the x-axis and temperature on the y-axis) for this system. Include the boiling
points of pure methanol, pure carbon tetrachloride, and the boiling point of the
azeotrope on your diagram.
b. Describe the behavior on distillation of a mixture that is 90% methanol and 10%
carbon tetrachloride.
After one component of the mixture has distilled off, the temperature is observed to
temporarily drop before it increases to the boiling point of the second component.
Explain this temperature drop.
Ethylene diamine (bp 116 °C) and water form a maximum boiling azeotrope
(bp 120 °C); the azeotropic mixture is 80% in ethylene diamine. SKETCH a distillation
curve (volume on the x-axis and temperature on the y-axis) to show what you would
expect to see should one distill 35 mL of a 50:50 mixture of these liquids. Be as
quantitatively accurate as possible (using graph paper).
W
15
MA
wwwww
me
PG
57% ¹
f
Wed 5:41 PM
Q
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Highlight Rotate Markup Search...
Transcribed Image Text:Preview File Edit View Go Tools Window Help 21,743 FEB 22 3. 4. 5. h (page 2 of 2) Given that a mixture of methanol and carbon tetrachloride forms a minimum-boiling- point azeotrope that boils at 55.7 °C with a composition of 20% methanol to 80% carbon tetrachloride: a. Construct an approximate boiling-point-phase diagram (with % composition on the x-axis and temperature on the y-axis) for this system. Include the boiling points of pure methanol, pure carbon tetrachloride, and the boiling point of the azeotrope on your diagram. b. Describe the behavior on distillation of a mixture that is 90% methanol and 10% carbon tetrachloride. After one component of the mixture has distilled off, the temperature is observed to temporarily drop before it increases to the boiling point of the second component. Explain this temperature drop. Ethylene diamine (bp 116 °C) and water form a maximum boiling azeotrope (bp 120 °C); the azeotropic mixture is 80% in ethylene diamine. SKETCH a distillation curve (volume on the x-axis and temperature on the y-axis) to show what you would expect to see should one distill 35 mL of a 50:50 mixture of these liquids. Be as quantitatively accurate as possible (using graph paper). W 15 MA wwwww me PG 57% ¹ f Wed 5:41 PM Q == Highlight Rotate Markup Search...
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