4 Pentacarbonyl iron (0), Fe(CO)s, was refluxed for 40h with an equal volume of dicyclopentadiene, C₁0H₁. The volatile material was removed in vacuum, and a crystalline compound was obtained by recrystallization of the residue. The molecular weight was determined by freezing point depression in benzene to be approximately 368 g/mole. Elemental analysis proved the following data: C: 47.55; H: 2.85; Fe: 31.52. The IR spectrum is shown below. Suggest a structure for the compound.
4 Pentacarbonyl iron (0), Fe(CO)s, was refluxed for 40h with an equal volume of dicyclopentadiene, C₁0H₁. The volatile material was removed in vacuum, and a crystalline compound was obtained by recrystallization of the residue. The molecular weight was determined by freezing point depression in benzene to be approximately 368 g/mole. Elemental analysis proved the following data: C: 47.55; H: 2.85; Fe: 31.52. The IR spectrum is shown below. Suggest a structure for the compound.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:4 Pentacarbonyl iron (0), Fe(CO)5, was refluxed for 40h with an equal volume of
dicyclopentadiene, C₁0H₁ The volatile material was removed in vacuum, and a
crystalline compound was obtained by recrystallization of the residue. The molecular
weight was determined by freezing point depression in benzene to be approximately
368 g/mole. Elemental analysis proved the following data: C: 47.55; H: 2.85; Fe: 31.52.
The IR spectrum is shown below. Suggest a structure for the compound.
4000 3000
Cm-1
1500
2000
1000
800
100
80---
60
40
20+
9
on
8
10
Wavelength, microns
11 12
13
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