3. For the following transformations draw the product in the box below. Draw only one stereoisomer in the boxif there is more than one. On the right side check the box(es) that corresponds to the product obtained from thereaction. Only organic products need to be provided.a)1 enantiomer(1 chiral compound)1:1 mix ofH20enantiomersBrmixture of23 °Cdiastereomersachiral1 enantiomerb)(1 chiral compound)1:1 mix ofenantiomersmixture of1) Nal2) KCNdiastereomersachiralc)1 enantiomerBr(1 chiral compound)1:1 mix ofKO'Buenantiomersmixture ofdiastereomersachirald)1 enantiomer(1 chiral compound)1:1 mix ofenantiomersmixture ofKO1)(1 equiv)HOSH2)diastereomersachiralBr1 enantiomer(1 chiral compound)1:1 mix ofenantiomerse)HOH2SO4heatmixture ofdiastereomersachiralf)1 enantiomer(1 chiral compound)1:1 mix ofenantiomersOCH3Br,CH3OHmixture ofdiastereomers23 °CH3COH.achiral

In case of c) we can't say we get a enatiomer because it is actually a distereomer. So in more…

3. For the following transformations draw the product in the box below. Draw only one stereoisomer in the box if there is more than one. On the right side check the box(es) that corresponds to the product obtained from the reaction. Only organic products need to be provided.

3. For the following transformations draw the product in the box below. Draw only one stereoisomer in the box if there is more than one. On the right side check the box(es) that corresponds to the product obtained from the reaction. Only organic products need to be provided.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

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3. For the following transformations draw the product in the box below. Draw only one stereoisomer in the box
if there is more than one. On the right side check the box(es) that corresponds to the product obtained from the
reaction. Only organic products need to be provided.
a)
1 enantiomer
(1 chiral compound)
1:1 mix of
H20
enantiomers
Br
mixture of
23 °C
diastereomers
achiral
1 enantiomer
b)
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
1) Nal
2) KCN
diastereomers
achiral
c)
1 enantiomer
Br
(1 chiral compound)
1:1 mix of
KO'Bu
enantiomers
mixture of
diastereomers
achiral
d)
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
KO
1)
(1 equiv)
HO
SH
2)
diastereomers
achiral
Br
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
e)
HO
H2SO4
heat
mixture of
diastereomers
achiral
f)
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
OCH3
Br,
CH3OH
mixture of
diastereomers
23 °C
H3CO
H.
achiral

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3. For the following transformations draw the major product in the box below. Draw only one stereoisomer in the box if there is more than one. On the right side check the box(es) that corresponds to the product obtained from the reaction, if one is provided. Only organic products need to be provided. a) Ph HBr 1 equiv b) NaH c) e) HO OH 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1) TsCl, pyridine 2 NaNj он H3PO heat 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1) SOBr2, pyridine 2) OH HBr excess g) 3- H2SO4 h) HA Br B CI j) ONa CH3 1) MsCI, TEA 2) Ясно ONa 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers…
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