3. For the following transformations draw the major product in the box below. Draw only one stereoisomer in the box if there is more than one. On the right side check the box(es) that corresponds to the product obtained from the reaction, if one is provided. Only organic products need to be provided. a) Ph HBr 1 equiv b) NaH c) e) HO OH 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1) TsCl, pyridine 2 NaNj он H3PO heat 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1) SOBr2, pyridine 2) OH HBr excess g) 3- H2SO4 h) HA Br B CI j) ONa CH3 1) MsCI, TEA 2) Ясно ONa 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral KO'Bu 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral нн 1) KI 2) NaN3 k) "al 1) NaH2 2) KO'Bu Br 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral OH 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral بچه همد Br 23
3. For the following transformations draw the major product in the box below. Draw only one stereoisomer in the box if there is more than one. On the right side check the box(es) that corresponds to the product obtained from the reaction, if one is provided. Only organic products need to be provided. a) Ph HBr 1 equiv b) NaH c) e) HO OH 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1) TsCl, pyridine 2 NaNj он H3PO heat 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1) SOBr2, pyridine 2) OH HBr excess g) 3- H2SO4 h) HA Br B CI j) ONa CH3 1) MsCI, TEA 2) Ясно ONa 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral KO'Bu 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral нн 1) KI 2) NaN3 k) "al 1) NaH2 2) KO'Bu Br 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral OH 1 enantiomer (1 chiral compound) 1:1 mix of enantiomers mixture of diastereomers achiral بچه همد Br 23
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Transcribed Image Text:3. For the following transformations draw the major product in the box below. Draw only one stereoisomer in
the box if there is more than one. On the right side check the box(es) that corresponds to the product obtained
from the reaction, if one is provided. Only organic products need to be provided.
a)
Ph
HBr
1 equiv
b)
NaH
c)
e)
HO
OH
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
1) TsCl, pyridine
2 NaNj
он
H3PO
heat
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
1) SOBr2, pyridine
2)
OH
HBr
excess
g)
3-
H2SO4
h)
HA
Br B
CI
j)
ONa
CH3
1) MsCI, TEA
2)
Ясно
ONa
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
KO'Bu
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
нн
1) KI
2) NaN3
k)
"al
1) NaH2
2)
KO'Bu
Br
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
OH
1 enantiomer
(1 chiral compound)
1:1 mix of
enantiomers
mixture of
diastereomers
achiral
بچه همد
Br
23
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