3. Complete the following assigned problem from the textbook. [10 pts] 14.44 Ignoring stereoisomers, draw all products that form by addition of HBr to (E)-hexa-1,3,5-triene. For full credit, (E)-hexa-1,3,5-triene • Use 'curly arrows' to denote electron flow. • Show all resonance forms of the reaction intermediate(s). Explicitly show reaction of the different resonance forms to make each product.
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- Please help me with the organic chemistry problem below: Consider the reaction below: (Check the attached image) (it is between Furan and maleic anhydride, a DIels-Alder reaction) a) Will this reaction for an endo product (with a melting point of 80-81 degrees) or the exo product (with a melitng point of 114 degrees)? b) Carefully explain why the product must have been formed the way it did (exo or endo). c) Provide a mechanism for this reaction.5. Write a detailed chemical mechanism for the following reaction. [10 pts] NBS hv ? For full credit, • Explicitly label initiation, propagation, and termination steps. • Use 'curly arrows' to denote electron flow. Show all resonance forms of the reaction intermediate(s). N-Br NBS (N-bromosuccinimde) • Show reaction at any resonance forms of the reaction intermediate(s) that lead to different products. including constitutional and stereochemical isomers (if any). Show two different termination steps. Showing more steps will not earn points; wrong steps will lose points3. An alkene can be converted into an ether in the three mechanistic steps shown below. Complete this mechanism by: Draw curved arrows to indicate the flow of electrons for each step. Lone pairs are omitted for clarity but be sure to include lone pairs on atoms that are involved in bond formation/breaking. Draw the reaction intermediates in the appropriate boxes. Include all nonzero formal charges. Classify each step of the mechanism using the boxes below each arrow as one of the following: acid- base proton transfer (AB), nucleophilic attack (NA), elimination (E), or rearrangement (R). + H-OMe H-OO + MeOH + MeOH + H-OMe H-OO 48
- Give a detailed reaction mechanism for the reaction expected to occur when 2-bromo-2- methylpentane is heated with sodium methoxide. • Draw clear structural formulas of all relevant species and use curved arrows to represent electron flow. Indicate which step is likely to be rate determining.6. Draw a plausible multi-step mechanism for the following transformation. Remember to use the correct arrow conventions for indicating electron flow and to keep track of relevant lone pairs and formal charges. Draw all products of each step, organic and inorganic. H S. Br Na : H SPlease load visual correctly on final answer
- .0. For 0.1 M equimolar reaction of CH3COOH + NH3 ----> CH3-CO-O™ + NH4+ How does the concentration of ]? [CH3COOH] compare to that of [CH3-CO-O (a) Equal (b) Greater than (c) Less than) (d) not possible determine aAnswer b and c only[Review Topics] [References) Draw a structural formula for the major product of the acid-base reaction shown. H2N. HCI (1 mole) (1 mole) You do not have to consider stereochemistry. • Do not include counter-ions, e.g., Na", I, in your answer. • In those cases in which there are two reactants, draw only the product from the compound that reacts. C P. opy eate
- Draw the mechanism of the following reaction, using the curved-arrow notation to indicate the reorganization of electron density. Show all intermediates, lone pairs, nonzero formal charges, countercharges, and reversibility or irreversibility. Finally, explain in detail why the observed regio- and stereochemistry is as shown. :Br: CH3 low [:Br] (CH3 + H-OH, :Br: excess H,0 (racemic)4) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors, the regiochemistry that results in each case. ỌMe Na, MeOH ? NH3 CHO Na, MeOH ? NH32. Draw all resonance structures for nitrobenzene and phenol below. Substituents on an aromatic ring can affect the rate of electrophilic aromatic substitution as well as the stereochemistry (ortho, meta, para) of the product. Briefly explain how this works. See Text: 15.10 (10th ed.) NO2 OH