3 2 CH3-CH2-CH2-OH Proton Chemical Shift (5) in ppm Carbon Chemical Shift (5) in ppm H1 C1 C2 H2 C3 H3 H4

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Kindly provide the structure for this nmr spectra using the data and information provided.

3. Fill in the table based on the data
Proton
H1
H2
H3
H4
13C NMR Spectrum
(150 MHz, CDCI, solution)
DEPT CH, CH, ↑ CH 1
proton decoupled
3
2
1
4
CH3-CH2-CH2-OH
Chemical Shift (5) in
ppm
Carbon
Chemical Shift (5) in
ppm
C1
C2
C3
solvent
T
200
160
120
80
40
0 ō (ppm)
¹H NMR Spectrum
(600 MHz, CDCl solution)
exchanges with
D₂O
expansions
↓
3.7
3.6
3.5
1.6
1.5
1.0
0.9
ppm
10 9
8 7 6 5
4
3
2
1
0
ō (ppm)
Transcribed Image Text:3. Fill in the table based on the data Proton H1 H2 H3 H4 13C NMR Spectrum (150 MHz, CDCI, solution) DEPT CH, CH, ↑ CH 1 proton decoupled 3 2 1 4 CH3-CH2-CH2-OH Chemical Shift (5) in ppm Carbon Chemical Shift (5) in ppm C1 C2 C3 solvent T 200 160 120 80 40 0 ō (ppm) ¹H NMR Spectrum (600 MHz, CDCl solution) exchanges with D₂O expansions ↓ 3.7 3.6 3.5 1.6 1.5 1.0 0.9 ppm 10 9 8 7 6 5 4 3 2 1 0 ō (ppm)
1.0
м
ppm
-0.5
1.5
2.0
H-H COSY Spectrum
(600 MHz, CDCI, solution)
2.5
4.5
15
3.0
3.5
-4.0
4.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0 0.5 ppm
H-C me-HSQC Spectrum
(600 MHz, CDCl solution)
ppm
10
10
20
-20
30
30
10
40
50
-50
60
60
Black cross-peaks CH and CH
Red cross-peaks CH
70
770
4.5 4.0 3.5
3.0 2.5
2.0
1.5 1.0 0.5 ppm
Transcribed Image Text:1.0 м ppm -0.5 1.5 2.0 H-H COSY Spectrum (600 MHz, CDCI, solution) 2.5 4.5 15 3.0 3.5 -4.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm H-C me-HSQC Spectrum (600 MHz, CDCl solution) ppm 10 10 20 -20 30 30 10 40 50 -50 60 60 Black cross-peaks CH and CH Red cross-peaks CH 70 770 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm
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