The 'H NMR spectrum of 1-nitronaphthalene recorded at 298K in CDC!3 solution is given below. The 2-dimensional 'H NOESY spectrum is given on the facing page. Given that the nitro group at position 1 will always extensively deshield the proton at position 8 such that it will appear as the resonance at lowest field in the spectrum, use the NOESY spectrum to assign all of the other protons in the spectrum. Hg NO2 1-nitronaphthalene H7. H3 H5 H4 'H NMR Spectrum (400 MHz, CDCI, sołution) solvent residual 8.8 8.6 8.4 8.2 8.0 7.8 7.6 7.4 7.2 ppm Proton Chemical Shift (8) in ppm H2 H3 H4 H5 H6 H7 H8 8.56
The 'H NMR spectrum of 1-nitronaphthalene recorded at 298K in CDC!3 solution is given below. The 2-dimensional 'H NOESY spectrum is given on the facing page. Given that the nitro group at position 1 will always extensively deshield the proton at position 8 such that it will appear as the resonance at lowest field in the spectrum, use the NOESY spectrum to assign all of the other protons in the spectrum. Hg NO2 1-nitronaphthalene H7. H3 H5 H4 'H NMR Spectrum (400 MHz, CDCI, sołution) solvent residual 8.8 8.6 8.4 8.2 8.0 7.8 7.6 7.4 7.2 ppm Proton Chemical Shift (8) in ppm H2 H3 H4 H5 H6 H7 H8 8.56
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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