2H2S(g) + SO2(g) = 3S(s) + 2H2O(9) At 298 K, the standard enthalpy change, AH°, for the reaction represented above is -145 kilojoules. (a) Predict the sign of the standard entropy change, ASº, for the reaction. Explain the basis for your prediction. (b) At 298 K, the forward reaction (i.e., toward the right) is spontaneous. What change, if any, would occur in the value of AG° for this reaction as the temperature is increased? Explain your reasoning using thermodynamic principles. (c) What change, if any, would occur in the value of the equilibrium constant, Keg, for the situation described in (b)? Explain your reasoning.
2H2S(g) + SO2(g) = 3S(s) + 2H2O(9) At 298 K, the standard enthalpy change, AH°, for the reaction represented above is -145 kilojoules. (a) Predict the sign of the standard entropy change, ASº, for the reaction. Explain the basis for your prediction. (b) At 298 K, the forward reaction (i.e., toward the right) is spontaneous. What change, if any, would occur in the value of AG° for this reaction as the temperature is increased? Explain your reasoning using thermodynamic principles. (c) What change, if any, would occur in the value of the equilibrium constant, Keg, for the situation described in (b)? Explain your reasoning.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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