2H2S(g) + SO2(g) = 3S(s) + 2H2O(9) At 298 K, the standard enthalpy change, AH°, for the reaction represented above is -145 kilojoules. (a) Predict the sign of the standard entropy change, ASº, for the reaction. Explain the basis for your prediction. (b) At 298 K, the forward reaction (i.e., toward the right) is spontaneous. What change, if any, would occur in the value of AG° for this reaction as the temperature is increased? Explain your reasoning using thermodynamic principles. (c) What change, if any, would occur in the value of the equilibrium constant, Keg, for the situation described in (b)? Explain your reasoning.

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2H2S(g) + SO2(g) = 3S(s) + 2H2O(9)
At 298 K, the standard enthalpy change, AH°, for the reaction
represented above is -145 kilojoules.
(a) Predict the sign of the standard entropy change, ASº, for
the reaction. Explain the basis for your prediction.
(b) At 298 K, the forward reaction (i.e., toward the right) is
spontaneous. What change, if any, would occur in the value of
AG° for this reaction as the temperature is increased? Explain
your reasoning using thermodynamic principles.
(c) What change, if any, would occur in the value of the
equilibrium constant, Keg, for the situation described in (b)?
Explain your reasoning.
Transcribed Image Text:2H2S(g) + SO2(g) = 3S(s) + 2H2O(9) At 298 K, the standard enthalpy change, AH°, for the reaction represented above is -145 kilojoules. (a) Predict the sign of the standard entropy change, ASº, for the reaction. Explain the basis for your prediction. (b) At 298 K, the forward reaction (i.e., toward the right) is spontaneous. What change, if any, would occur in the value of AG° for this reaction as the temperature is increased? Explain your reasoning using thermodynamic principles. (c) What change, if any, would occur in the value of the equilibrium constant, Keg, for the situation described in (b)? Explain your reasoning.
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