25. The solvolysis of several tertiary p-nitrobenzoate esters in aqueous acetone occurs at different relative rates, depending on the substituent R. Look at the structure of the substituent and rank the relative rates of solvolysis, assigning 1 to the most reactive and 4 to the least reactive. CH3 O R-C-0-8- CH3 CH3 R-C-OH CH3 H2O/Acetone -NO2 R Ph i-C3H, CH3 t-C4H9 3
Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 3 images
