22) Pyridoxal pyrophosphate (PLP) can catalyze both a,ß-elimination reactions and B,y-elimination reactions. Propose a mechanism for the following PLP-catalyzed B.y-elimination. X-CH₂CH₂C-COO- NH₂* ΡΙΟ OH enzyme CH₂CH₂C-COO- +X*+NH4* !!

22) Pyridoxal pyrophosphate (PLP) can catalyze both a,ß-elimination reactions and B,y-elimination reactions. Propose a mechanism for the following PLP-catalyzed B.y-elimination. X-CH₂CH₂C-COO- NH₂* ΡΙΟ OH enzyme CH₂CH₂C-COO- +X+NH4 !!

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

22) Pyridoxal pyrophosphate (PLP) can catalyze both a,ß-elimination reactions and
B,y-elimination reactions. Propose a mechanism for the following PLP-catalyzed
B.y-elimination.
H
X-CH₂CH₂C-COO-
NH3*
Pio
OH
enzyme
CH₂CH₂C-COO- +X+ NH4*
!!

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