Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please show all solutions. And please balnce using half reaction method following the the steps shown in the second picture. Thank you.
![Steps in the Half-Reaction Method The balancing process begins with a "skel-
eton" ionic reaction that consists of only species that are oxidized and reduced. Here
are the steps in the half-reaction method:
Step 1. Divide the skeleton reaction into two half-reactions, each of which contains the
oxidized and reduced forms of one of the species: if the oxidized form of a species
is on the left side, the reduced form must be on the right, and vice versa.
Step 2. Balance the atoms and charges in each half-reaction.
Atoms are balanced in this order: atoms other than O and H, then O, then H.
Charge is balanced by adding electrons (e-) to the left side in the reduction
half-reaction because the reactant gains them and to the right side in the
oxidation half-reaction because the reactant loses them.
Step 3. If necessary, multiply one or both half-reactions by an integer so that
number of e gained in reduction
number of e- lost in oxidation
%3D
Step 4. Add the balanced half-reactions, and include states of matter.
Step 5. Check that the atoms and charges are balanced.
Let's balance a redox reaction that occurs in acidic solution and then see how to bal-
ance one in basic solution in Sample Problem 21.1.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F80b704b9-18f6-4f9e-b0cf-2ce8c1ccfe74%2F2845a9be-19f6-42dd-9115-fd846c58301f%2Febxklyy_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Steps in the Half-Reaction Method The balancing process begins with a "skel-
eton" ionic reaction that consists of only species that are oxidized and reduced. Here
are the steps in the half-reaction method:
Step 1. Divide the skeleton reaction into two half-reactions, each of which contains the
oxidized and reduced forms of one of the species: if the oxidized form of a species
is on the left side, the reduced form must be on the right, and vice versa.
Step 2. Balance the atoms and charges in each half-reaction.
Atoms are balanced in this order: atoms other than O and H, then O, then H.
Charge is balanced by adding electrons (e-) to the left side in the reduction
half-reaction because the reactant gains them and to the right side in the
oxidation half-reaction because the reactant loses them.
Step 3. If necessary, multiply one or both half-reactions by an integer so that
number of e gained in reduction
number of e- lost in oxidation
%3D
Step 4. Add the balanced half-reactions, and include states of matter.
Step 5. Check that the atoms and charges are balanced.
Let's balance a redox reaction that occurs in acidic solution and then see how to bal-
ance one in basic solution in Sample Problem 21.1.
![21.31 Balance each skeleton reaction, calculate El and state
whether the reaction is spontaneous:
(a) Co(s) + H* (aq)
(b) Mn2 (aq) + Br,(1)
(c) Hg,2 (aq)
cell
Co2+(aq) + H,(g)
MnO, (aq) + Br (aq) [acidic]
->
Hg2 (aq) + Hg(1)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F80b704b9-18f6-4f9e-b0cf-2ce8c1ccfe74%2F2845a9be-19f6-42dd-9115-fd846c58301f%2Fssllh1s_processed.jpeg&w=3840&q=75)
Transcribed Image Text:21.31 Balance each skeleton reaction, calculate El and state
whether the reaction is spontaneous:
(a) Co(s) + H* (aq)
(b) Mn2 (aq) + Br,(1)
(c) Hg,2 (aq)
cell
Co2+(aq) + H,(g)
MnO, (aq) + Br (aq) [acidic]
->
Hg2 (aq) + Hg(1)
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