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- 1. A symmetric infinite well has the potential energy V(x) = { |x| a a. Write the corresponding Schrodinger equation and its solutions b. Write the boundary conditions c. Obtain the eigenfunctions and eigenvaluesA particle moves in an attractive central potential V(r) = -9²/r3/2. Use the variational principle to find an upper bound to the lowest s-state energy. Use a hydrogenic wave function as your trial function. %3D1) Make use of a translation operator and prove Bloch's theorem in the form : y (F+R)=e¹ky (7). An alternative equivalent form for Bloch's theorem is that the wavefunction has the form 7)=eku (F) where u (F) is lattice periodic. By substituting this into the Schrodinger equation explain the origin of energy bands.
- 3. Plane waves and wave packets. In class, we solved the Schrodinger equation for a "free particle" (e.g. when U(x,t) = 0). The correct[solution is (x, t) = Ae(px-Et)/ħ This represents a "plane wave" that exists for all x. However, there is a strange problem with this: if you try to normalize the wave function (determine A by integrating * for all x), you will find an inconsistency (A has to be set equal to 0?). This is because the plane wave stretches to infinity. In order to actually represent a free particle, this solution needs to be handled carefully. Explain in words (and/or diagrams) how we can construct a "wave packet" from the plane wave solution. (Hint 1: consider a superposition of plane waves for a limited range of momentum/energy. Hint 2: have a look at the brief discussion in the middle of pg. 278 and especially pg. 308-309 of the text.)Question A2 Consider an infinite square well of width L, with V = 0 in the region -L/2 < x < L/2 and V → ∞ everywhere else. For this system: a) Write down and solve the time-independent Schrödinger equation for & inside the well, where -L/2< x9Consider the sheet formed by the intersection of the curves: x = 0, x = 4, y = 0, y = 3 [=] cm, with a variable density of mass per unit area ρ(x,y) = xy [=] g/cm2 . Write and evaluate multiple integrals to calculate the following: a. The area of the sheet [=] cm2 . b. The mass of the sheet [=] g. c. The shell moments about the x & y axes (Mx & My) [=] g∙cm. d. The position of the center of mass of the sheet ( , ) [=] cm.4. Consider a quantum 3-it initially in the state |v) e Cº. Suppose that the 3-it undergoes a reversible evolution associated with the unitary matrix A, immediately after which a measurement of the observable B is performed. What is (B) for this measurement if 0 0 -i A = (0 1 1 0 0 0 -i 0 0 |v) and B = |? (Express your result as an explicit real number.)Consider an electron trapped in a 20 Å long box whose wavefunction is given by the following linear combination of the particle's n = 2 and n = 3 states: ¥(x,t) =, 2nx - sin ´37x - sin 4 where E, 2ma² a a. Determine if this wavefunction is properly normalized. If not, determine an appropriate value for a normalization constant. b. Show that this is not an eigenfunction to the PitB problem. What are the possible results that could be returned when the energy is measured and what are the probabilities of measuring each of these results?4. A particle is in the state 2 1 Y (0,0)+ V5 Y, '(0,ø) – Y (0,¢), V5 which is a superposition of the normalized eigenstates, Y;" (0,¢), of the L² operator. Calculate the value of the total angular momentum of the particle in this state. Also, calculate the expectation value of the operator L+L_ in this state.A. Time evolution in a symmetric well. A particle of mass m moves freely inside a symmetric infinite well of width a. At t = 0 it has the wave function: (x,0)= 1) Determine A so that the wavefunction is normalized. √a 3 37x 1 + 5a Cos cos Cos 57x a1.The odd parity eigenstates of the infinte square well , with potential V = 0 in the range −L/2 ≤ ? ≤ L/2, are given by : (see figure) and have Ψn(x, t) = 0 elsewhere , for n=2 , 4 , 6 etc a) Sketch the potential of this system , including in your sketch the positions of the lowest three energy levels . Indicate in your sketch the form of the wavefunction for a particle in each of these energy levels , and state which of the wavefunctions you have drawn could be decirbed by the Ψn written above (see figure) . b) Calculate the expectation value of momentum , ⟨p⟩ for a particle with n=2 c) Calculate the expectation value of momentum squared ⟨p 2⟩ , for a particle with n = 2 . Hint : you may use the mathematical identiy sin2 x = 1/2 (1 − cos 2x) without proof .SEE MORE QUESTIONS