2 A student determined the concentration of a weak acid, acetic acid, by a titrimetric method using a standard NaOH solution and a pH meter for end point detection. Table 1.0 below shows the data that was obtained by the student. Table 1.0: Potentiometric titration of acetic acid with 0.100 M standard NaOH solution Burette Reading Volume of NaOH added (mL) pH reading 11.54 0 3.14 12.25 0.71 3.70 13.40 1.86 4.16 16.59 5.05 4.77 17.50 5.96 4.93 19.35 7.81 5.24 20.41 8.87 5.49 21.00 9.46 5.68 21.60 10.06 5.96 21.83 10.29 6.14 22.01 10.47 6.34 22.12 10.58 6.48 22.20 10.66 6.68 22.30 10.76 6.97 22.38 10.84 7.73 22.41 10.87 9.21 22.49 10.95 10.04 22.55 11.01 10.57 22.61 11.07 10.83 23.00 11.46 11.35 23.31 11.77 11.62 23.71 12.17 11.76 24.30 12.76 11.89 25.20 13.66 12.03 Plot the 2nd derivative curve and also determine the end point а b. C.

2 A student determined the concentration of a weak acid, acetic acid, by a titrimetric method using a standard NaOH solution and a pH meter for end point detection. Table 1.0 below shows the data that was obtained by the student. Table 1.0: Potentiometric titration of acetic acid with 0.100 M standard NaOH solution Burette Reading Volume of NaOH added (mL) pH reading 11.54 0 3.14 12.25 0.71 3.70 13.40 1.86 4.16 16.59 5.05 4.77 17.50 5.96 4.93 19.35 7.81 5.24 20.41 8.87 5.49 21.00 9.46 5.68 21.60 10.06 5.96 21.83 10.29 6.14 22.01 10.47 6.34 22.12 10.58 6.48 22.20 10.66 6.68 22.30 10.76 6.97 22.38 10.84 7.73 22.41 10.87 9.21 22.49 10.95 10.04 22.55 11.01 10.57 22.61 11.07 10.83 23.00 11.46 11.35 23.31 11.77 11.62 23.71 12.17 11.76 24.30 12.76 11.89 25.20 13.66 12.03 Plot the 2nd derivative curve and also determine the end point а b. C.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Consider the weak acid titration curve below. At what approximate volume of added NaOH will the pH of the solution be equal to the pKa of acid? pH Curve 14 12 10 8 pH 6. 4 6. 10 12 14 16 18 20 22 Volume of titrant / mL 5.0 mL 2.5 mL this cannot be determined without the volume of the acid solution 10.0 mL this cannot be determined without the Ka value for the acid 2. 2.
A titration was performed where a weak acid was titrated with a strong base. Use the following graph of the titration curve to estimate the volume of the strong base, along the x-axis, that was dispensed to reach the equivalence point. 14.00- 12.00- 10.00- 8.00- 6.00- 4.00 2.00- ● ● ● 0.00- 0.00 5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 Volume (ml)
You are given a solution that contains a mixture of two weak acids. You take a 50.00 mL sample of the mixture and titrate it with 0.1000M NaOH using a pH meter. You obtain the data shown in the plot below. 12 10 8 6 4 2 0 0 5 Titration of a mixture 10 15 vol (mL) NaOH added 20 25 30 Determine the first and second equivalence volumes. Use the equivalence volumes to determine how many moles of NaOH was used to titrate each acid. Use those values to determine the concentration of each acid in the original mixture. Finally, estimate the pKa values for each acid from the plot. Show your calculations and explain any choices you have made.
Determine the pH at the point in the titration of 40.0 mL of 0.200 M H2NNH2 with 0.100 M HNO3 after 100.0 mL of the strong acid has been added. The value of Kb for H,NNH, is 3.0 × 10-6. ( PREV 1 Based on the result of the acid-base reaction, determine the pH of the solution. pH RESET 6.21 7.79 11.3 2.70 1.85 1.70 3.91 10.1 12.3 3.70 17.7
For each scenario below, select the color of the solution using the indicator thymol blue during the titration. When you first add indicator to your Na₂CO3 solution, the solution is basic (pH ~10), and the color is [Select] At the equivalence point for the titration, the moles of added HCI are equal to the moles of Na₂CO3. One drop (or less!) past this is called the endpoint. The added HCI begins to titrate the thymol blue indicator itself. At the endpoint, the indicator color is [Select] When you weren't paying attention and added too much HCI (~12 mL extra), the color is [Select] When you really weren't paying attention and reached the second equivalence point of Na₂CO3, the color is [Select ]
Titration Curve Using the table of indicators identify which of the given 13 12 indicators would be appropriate for the titration 11 10 represented in the titration curve. 9 thymol blue 8 pH 7 6 alizarin yellow R 5 O quinaldine red 4 3 O clayton yellow 2 1 metacresol purple 4 6 8 10 12 14 16 18 20 Volume of Titrant (mL) O methyl green 2.
aching and le The following graph shows the pH curve for the titration of 25 mL of a 0.1 M monoprotic acid solution with a 0.1 M solution of a monoprotic base. 14 pH 12 10 4 10 15 20 25 30 35 40 45 50 mL of 0.1 M base added (1) The pH curve represents the'titration of a acid with a base. (2) Choose a suitable indicator for the endpoint of the titration from the following pulldown list. Malachite green 0.2 1.8 Thymol blue 1.2 2.8 8.0 9.6 Previous Next Methyl orange Email Instructor Save and E ENG 令口 US Home 8. 9.
Interpret pH titration plots. Answer the following about the titration plot shown below, involving a monoprotic acid and base. 20 mL of 0.1M titrand titrated with 0.1M titrant. Data points at 1 mL increments. 14.0 12.0 10.0 5 8.0 6.0 4.0 2.0 0.0 seededood 0 0.0 10.0 مهمه 20.0 30.0 Volume of titrant (mL) (a) Is the species being titrated an acid or a base? (b) Is the species being titrated strong or weak? (c) What is the value of Ka (if a weak acid) or K, (if a weak base) for the species being titrated? If the species is strong (100% dissociated), enter 999. rààààààààà 40.0 50.0
Determine the pH at the point in the titration of 40.0 mL of 0.200 M HNNH2 with 0.100 M HNO: after 10.0 mL of the strong acid has been added. The value of Kb for H2NNH2 is 3.0 x 10-6. PREV 1 2 4 NEXT > Based on your ICE table and definition of Kb, set up the expression for Kb in order to determine the unknown. Do not combine or simplify terms. = 3.0 x 10-6 RESET [0] [0.200] [0.0200] [0.100] [0.140] [0.175] [x] [2x] [0.200 + x] [0.200 - x] [0.0200 + x] [0.0200 - x] [0.100 + x] [0.100 - x] [0.140 + x] [0.140 - x] [0.175 + x] [0.175 - x]
Determine the pH at the point in the titration of 40.0 mL of 0.200 M H2NNH2 with 0.100 M HNO3 after 10.0 mL of the strong acid has been added. The value of Kb for H2NNH2 is 3.0 x 10-6. 1 2 4 NEXT Use the table below to determine the moles of reactant and product after the reaction of the acid and base. H2NNH2(aq) H*(aq) H2NNH;*(aq) + Before (mol) Change (mol) After (mol) 5 RESET 0.200 0.100 +x 0.200 + x 0.200 - x -x 0.100 + x 0.100 - x 1.00 x 103 -1.00 x 10-3 2.00 x 10-3 -2.00 x 10-3 6.00 x 103 -6.00 x 10-3 7.00 x 10-3 -7.00 x 103 8.00 x 103 -8.00 x 103
For each scenario below, select the color of the solution using the indicator thymol blue during the titration. When you first add indicator to your Na2CO3 solution, the solution is basic (pH ~10), and the color is [Select] At the equivalence point for the titration, the moles of added HCI are equal to the moles of Na2CO3. One drop (or less!) past this is called the endpoint. The added HCI begins to titrate the thymol blue indicator itself. At the endpoint, the indicator color is [Select] When you weren't paying attention and added too much HCI (~12 mL extra), the color is [Select] When you really weren't paying attention and reached the second equivalence point of Na2CO3, the color is ✓ [Select] blue yellow red orange green Question 9
Thank you! Data included in pictures! No hand drawn graphs!! Determine the equivalence point and the endpoint of the sudsy ammonia/citric acid reaction by graphing the titration data (pH vs volume citric acid) from Table 3: Titration of Sudsy Ammonia with 0.25 M Citric Acid Data with the Chosen Indicator. Draw a green arrow (use ‘Insert Shape’ feature to do this once you have copied your graph from Excel) on your graph indicating the data point that represents your equivalence point. Draw a blue arrow (use ‘Insert Shape’ feature to do this once you have copied your graph from Excel) on your graph indicating the data point that represents your endpoint. Use a graphing software to create the x-y scatter plot showing the pH of the experimental solution as a function of the volume of citric acid (the titrant) added for the titration data in Question 9. On your graph, the x-axis should be the volume of citric acid added (mL), and the y-axis should be the pH of the experimental…