1a) Hexane, CH3(CH2)4CH3, is found to have a long retention time when separated from a mixture. A column with a C18 (18-carbon chain) stationary phase and a methanol-water modal phase is used for the separation. Explain why hexane has a long retention time. 1b)You wish to chromatographically seperate a mixtureof the follwing compunds. Which of the two compounds will

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
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1a) Hexane, CH3(CH2)4CH3, is found to have a long retention time when separated from a mixture. A column with a C18 (18-carbon chain) stationary phase and a methanol-water modal phase is used for the separation. Explain why hexane has a long retention time.

1b)You wish to chromatographically seperate a mixtureof the follwing compunds. Which of the two compounds will be most difficult to seperatate from one another? Why?

 

(a) CH;CH,CH,COH
CH,
(b)
CH,CHCH,CH,CH,CH,CH,CH,OH
CH3
(c) CH;CH,CH,CHCH,CH,CH,CH3
(d) CH;CH2OCH;CH;CH;CH3
CH3
OH
(e) CH,CHCH,CH,CH,CHCH,CH3
Transcribed Image Text:(a) CH;CH,CH,COH CH, (b) CH,CHCH,CH,CH,CH,CH,CH,OH CH3 (c) CH;CH,CH,CHCH,CH,CH,CH3 (d) CH;CH2OCH;CH;CH;CH3 CH3 OH (e) CH,CHCH,CH,CH,CHCH,CH3
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