18. A compound is known to have a free amino group with a pK, of 8.8, and one other ionizable group with a pK, between 5 and 7. To 100 mL of a 0.2 M solution of this compound at pH 8.2 was added 40 mL of a solution of 0.2 M hydrochloric acid. The pH changed to 6.2. The pk₁ of the second ionizable group is: A) The pH cannot be determined from this information. B) 5.4. C) 5.6. D) 6.0. E) 6.2.

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18. A compound is known to have a free amino group with a pK, of 8.8, and one other
ionizable group with a pK, between 5 and 7. To 100 mL of a 0.2 M solution of this
compound at pH 8.2 was added 40 mL of a solution of 0.2 M hydrochloric acid. The
pH changed to 6.2. The pk, of the second ionizable group is:
A) The pH cannot be determined from this information.
B)
5.4.
C) 5.6.
D) 6.0.
E) 6.2.
Transcribed Image Text:18. A compound is known to have a free amino group with a pK, of 8.8, and one other ionizable group with a pK, between 5 and 7. To 100 mL of a 0.2 M solution of this compound at pH 8.2 was added 40 mL of a solution of 0.2 M hydrochloric acid. The pH changed to 6.2. The pk, of the second ionizable group is: A) The pH cannot be determined from this information. B) 5.4. C) 5.6. D) 6.0. E) 6.2.
Expert Solution
Step 1

Given that:

Volume of solution = 100 mL

Concentration of solution = 0.2 M

Volume of HCl = 40 mL

Concentration of HCl = 0.2 M

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