16.96 Experiment shows that the rate of formation of carbon tetrachloride from chloroform, CHCl3 (g) + Cl2 (g) → CCl4 (g) + HCl (g) 1 3 is first order in CHCl3, order in Cl₂, and order overall. Show that the following mechanism is consistent with the rate law: (1) Cl₂ (g)=2C1 (g) [fast] (2) C1 (g) + CHCl3 (g) → HCl (g) + CC13 (g) [slow] (3) CC13 (g) +Cl (g) → CC14 (g) [fast]

16.96 Experiment shows that the rate of formation of carbon tetrachloride from chloroform, CHCl3 (g) + Cl2 (g) → CCl4 (g) + HCl (g) 1 3 is first order in CHCl3, order in Cl₂, and order overall. Show that the following mechanism is consistent with the rate law: (1) Cl₂ (g)=2C1 (g) [fast] (2) C1 (g) + CHCl3 (g) → HCl (g) + CC13 (g) [slow] (3) CC13 (g) +Cl (g) → CC14 (g) [fast]

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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