15. The potential of butyl alcohol as an automobile fuel is immense. Butanol at 85 percent strength can be used in cars designed for gasoline without any change to the engine (unlike 85% ethanol), and it produces more power than ethanol and almost as much power as gasoline, so the miles per gallon will also almost match that of gasoline. It is formed from butyl chloride according to the following kinetic process:
15. The potential of butyl alcohol as an automobile fuel is immense. Butanol at 85 percent strength can be used in cars designed for gasoline without any change to the engine (unlike 85% ethanol), and it produces more power than ethanol and almost as much power as gasoline, so the miles per gallon will also almost match that of gasoline. It is formed from butyl chloride according to the following kinetic process:
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
![13
15. The potential of butyl alcohol as an automobile fuel is immense. Butanol at 85 percent
strength can be used in cars designed for gasoline without any change to the engine (unlike
85% ethanol), and it produces more power than ethanol and almost as much power as
gasoline, so the miles per gallon will also almost match that of gasoline. It is formed from
butyl chloride according to the following kinetic process:
C4H9C1 (g) + H₂O → C4H9OH (aq) + HCl (aq)
a. Using the following graphical representation, estimate the half-life of this reaction.
Use two significant figures for your answer.
b.
Assuming this reaction follows first order kinetics with respect to C4H9C1, and is
zero order with respect to water, calculate the rate constant for this reaction at this
particular temperature. Use two significant figures for your answer. Use appropriate
units.
000.05 306.07
() [1]
0.1
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0
Instantaneous
rate at
1=0
(initial rate)
DI
h
Instantaneous
rate at
1=600 s
100 200 300 400 500 600 700 800 900
Time (s)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F55b8ef5e-ccaa-4ebe-b7cb-744f55a24c3b%2F7c532885-2dd3-49b7-9ef5-275c668c246e%2F2np4098_processed.jpeg&w=3840&q=75)
Transcribed Image Text:13
15. The potential of butyl alcohol as an automobile fuel is immense. Butanol at 85 percent
strength can be used in cars designed for gasoline without any change to the engine (unlike
85% ethanol), and it produces more power than ethanol and almost as much power as
gasoline, so the miles per gallon will also almost match that of gasoline. It is formed from
butyl chloride according to the following kinetic process:
C4H9C1 (g) + H₂O → C4H9OH (aq) + HCl (aq)
a. Using the following graphical representation, estimate the half-life of this reaction.
Use two significant figures for your answer.
b.
Assuming this reaction follows first order kinetics with respect to C4H9C1, and is
zero order with respect to water, calculate the rate constant for this reaction at this
particular temperature. Use two significant figures for your answer. Use appropriate
units.
000.05 306.07
() [1]
0.1
0.09
0.08
0.07
0.06
0.05
0.04
0.03
0.02
0.01
0
Instantaneous
rate at
1=0
(initial rate)
DI
h
Instantaneous
rate at
1=600 s
100 200 300 400 500 600 700 800 900
Time (s)
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 7 images
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The