13. Draw the Lewis structures and predict the hybridization (sp, sp², sp³), geometry (linear, trigonal, tetrahedral) and bond angles (180°, 120°, 109.5°) for the central atoms in the following compounds. a. Nin NH3 b. O in H2O c. Cin CH3CHCHCH3 d. C and N in CH3CHNH e. C and N in C CH3CN

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Topic: STRUCTURE AND BONDING

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13. Draw the Lewis structures and predict the hybridization (sp, sp?, sp3),
geometry (linear, trigonal, tetrahedral) and bond angles (180°, 120°, 109.5°)
for the central atoms in the following compounds.
a. Nin NH3
b. O in H2O
d. C and N in CH3CHNH
e. C and N in C CH3CN
c. Cin CH3CHCHCH3
14. Which of the following compounds show cis-trans isomerism? Draw the cis
and trans isomers of those that do.
a. CHF=CHF
b.
c. F2C=CH2
-CHCH,
15. Identify whether the following pairs of structures are: (A) Same compound,
(B) Constitutional isomers, (C) Cis-trans isomers or (D) Not isomers.
а. (i)
CH,CH,CHCH,CH, and CH,CH,CHCH,CH,CH,
T.
ČH,CH,
(ii)
1,
CH3
b. (i)
Br
(ii)
Br.
Br
and
C=C
H
H
(i)
Br
H.
С.
(ii)
Br
H
Br.
C=
and
H
Br
Br
H.
d. (i)
Br
(ii)
H.
Br
C=
and
H
Br
Br
(ii)
Cl Cl
H.
е.
(i)
H Cl
| |
Н—С—С—Н
and
Н—С—С—Н
ČI H
H H
Transcribed Image Text:13. Draw the Lewis structures and predict the hybridization (sp, sp?, sp3), geometry (linear, trigonal, tetrahedral) and bond angles (180°, 120°, 109.5°) for the central atoms in the following compounds. a. Nin NH3 b. O in H2O d. C and N in CH3CHNH e. C and N in C CH3CN c. Cin CH3CHCHCH3 14. Which of the following compounds show cis-trans isomerism? Draw the cis and trans isomers of those that do. a. CHF=CHF b. c. F2C=CH2 -CHCH, 15. Identify whether the following pairs of structures are: (A) Same compound, (B) Constitutional isomers, (C) Cis-trans isomers or (D) Not isomers. а. (i) CH,CH,CHCH,CH, and CH,CH,CHCH,CH,CH, T. ČH,CH, (ii) 1, CH3 b. (i) Br (ii) Br. Br and C=C H H (i) Br H. С. (ii) Br H Br. C= and H Br Br H. d. (i) Br (ii) H. Br C= and H Br Br (ii) Cl Cl H. е. (i) H Cl | | Н—С—С—Н and Н—С—С—Н ČI H H H
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