12. Phosphorus pentachloride exists at equilibrium with phosphorus trichloride and chlorine: PCIS → PCla@ + Ca (B) A sample of PCl, with an initial concentration ([PCL) of 3.00 M is placed in an empty container and allowed to react. When the system reaches equilibrium, the concentrations of PCla and Cla are both 1.80 M ([PCL1 = 1.80 M and [Cl] = 1.80 M). a) Calculate the equilibrium concentration of PCl: ([PC:). Show all work. b) Write the equilibrium expression for the reaction above. c) Find the value of the equilibrium constant (K). Show all work. d) Indicate which side of the reaction is favored. Explain how you know. e) Assuming the reaction is endothermic (PCls (2). + Energy PCl3 + Chw), identify two ways in which the equilibrium can be stressed to increase the production of PCl3.
12. Phosphorus pentachloride exists at equilibrium with phosphorus trichloride and chlorine: PCIS → PCla@ + Ca (B) A sample of PCl, with an initial concentration ([PCL) of 3.00 M is placed in an empty container and allowed to react. When the system reaches equilibrium, the concentrations of PCla and Cla are both 1.80 M ([PCL1 = 1.80 M and [Cl] = 1.80 M). a) Calculate the equilibrium concentration of PCl: ([PC:). Show all work. b) Write the equilibrium expression for the reaction above. c) Find the value of the equilibrium constant (K). Show all work. d) Indicate which side of the reaction is favored. Explain how you know. e) Assuming the reaction is endothermic (PCls (2). + Energy PCl3 + Chw), identify two ways in which the equilibrium can be stressed to increase the production of PCl3.
Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.35PAE: In the reaction in Exercise 12.33, another trial was carried out. The reaction began with an initial...
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![12. Phosphorus pentachloride exists at equilibrium with phosphorus
trichloride and chlorine:
PCI5 (2) = PCla + Clae
A sample of POCI, with an initial concentration ([PCL) of 3.00M is placed in an empty
container and allowed to react. When the system reaches equilibrium, the concentrations
of PCla and Cla are both 1.80 M ([PCL] = 1.80 M and [Cl] = 1.80 M).
a) Calculate the equilibrium concentration of PCl: ([PCL). Show all work.
b) Write the equilibrium expression for the reaction above.
c) Find the value of the equilibrium constant (K). Show all work.
d) Indicate which side of the reaction is favored. Explain how you know.
e) Assuming the reaction is endothermic (PCls (2) + Energy PCae
+ Chw),
identify two ways in which the equilibrium can be stressed to increase the production
of PCla.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F568f6bdd-bb57-4ef6-85de-b375d9807015%2F01a6ca44-ead3-454a-a55a-112b1a1d95ab%2Fwm5i61c_processed.jpeg&w=3840&q=75)
Transcribed Image Text:12. Phosphorus pentachloride exists at equilibrium with phosphorus
trichloride and chlorine:
PCI5 (2) = PCla + Clae
A sample of POCI, with an initial concentration ([PCL) of 3.00M is placed in an empty
container and allowed to react. When the system reaches equilibrium, the concentrations
of PCla and Cla are both 1.80 M ([PCL] = 1.80 M and [Cl] = 1.80 M).
a) Calculate the equilibrium concentration of PCl: ([PCL). Show all work.
b) Write the equilibrium expression for the reaction above.
c) Find the value of the equilibrium constant (K). Show all work.
d) Indicate which side of the reaction is favored. Explain how you know.
e) Assuming the reaction is endothermic (PCls (2) + Energy PCae
+ Chw),
identify two ways in which the equilibrium can be stressed to increase the production
of PCla.
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