11. Suppose an obligate aerobic chemolithotroph was able to use any of the potential energy sources listed in the table below as a source of electrons. Which energy source (i.e., electron donor: I want the molecule not the redox couple) would provide the greatest amount of free energy? (Note: all the redox couples listed are two electron transfers). Explain your answer – MATH works well for this. Redox Couple 2H H, -0.42 +0.42 NO, NO, +0.82 s'ms -0.28 S'H,S 2- +0.02 6.
11. Suppose an obligate aerobic chemolithotroph was able to use any of the potential energy sources listed in the table below as a source of electrons. Which energy source (i.e., electron donor: I want the molecule not the redox couple) would provide the greatest amount of free energy? (Note: all the redox couples listed are two electron transfers). Explain your answer – MATH works well for this. Redox Couple 2H H, -0.42 +0.42 NO, NO, +0.82 s'ms -0.28 S'H,S 2- +0.02 6.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:11. Suppose an obligate aerobic chemolithotroph was able to use any of the potential energy sources listed in the table below as a
source of electrons. Which energy source (i.e., electron donor: I want the molecule not the redox couple) would provide the
greatest amount of free energy? (Note: all the redox couples listed are two electron transfers). Explain your answer – MATH
works well for this.
Redox Couple
Po
-0.42
2H H2
+0.42
NO, NO,
%0H0
+0.82
s'H,S
so, s0,"
-0.28
2-
2-
+0.02
12. Consider a redox reaction involving the redox couples S/H2S and NO3/NO, in the above table.
(a) Which molecule (I want the molecule, not the redox couple) would be the electron acceptor? Why? Use the table above to
help answer this question.
(b) (Suppose a chemoorganotroph could acquire electrons from H2 using either oxygen or nitrate (NO3) as the terminal
electron acceptor. Per two electrons transferred, determine if the use of nitrate or oxygen will yield more energy? You must
show how you arrived at this by showing your work in order to receive full credit for your answer. It's all in the math!
Option (A): H2 +½ O2 = H2O
Option (B): H2 + NO3¯=NO2¯ +H2O
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