Please answer very soon will give rating surelyComplete Answer needed c. Consider the two Pt complexes shown below. Discuss the oxidation states of the two Pt centers alongwith the bonding details between the alkyne ligands and the Pt center. What is the charge and bond orderfor the "triple-bond" in the alkyne ligand for each complex? Some useful information: C=C triple bondlength in a free alkyne = 1.19 Å; C=C double bond length in alkenes = 1.35 Å; C-C single bond length =1.54 Å.Complex ACH3Ph2MeP-Pt-PMePh2H3CCH3Pt-CH, = 2.10 APt-PR, = 2.29 ÁPt-alkyne = 2.28 AC=C = 1,22 AMe-C=C = 164°Alkyne C=C carbons are perpendicularto the square plane of the complex (Pt,P, & CH3 atoms)Complex BPh3PPPH3CIPt-PR3 = 2.28 APt-alkyne = 2.05 ÁC=C = 1.38 ÂMe-C=C = 134°Alkyne carbons are in the squareplane of the complex

Bond order: It defines the no. of bonds shared between two atoms. It is the difference between…

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Chemistry: The Molecular Science

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Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 105QRT

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Photochemistry is the part of chemistry that studies the various mechanisms of reactions that are triggered by the presence of light energy. It also helps to study the changes involved in a molecule that can undergo the absorption of radiation.

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Complete Answer needed

c. Consider the two Pt complexes shown below. Discuss the oxidation states of the two Pt centers along
with the bonding details between the alkyne ligands and the Pt center. What is the charge and bond order
for the "triple-bond" in the alkyne ligand for each complex? Some useful information: C=C triple bond
length in a free alkyne = 1.19 Å; C=C double bond length in alkenes = 1.35 Å; C-C single bond length =
1.54 Å.
Complex A
CH3
Ph2MeP-
Pt
-PMePh2
H3C
CH3
Pt-CH, = 2.10 A
Pt-PR, = 2.29 Á
Pt-alkyne = 2.28 A
C=C = 1,22 A
Me-C=C = 164°
Alkyne C=C carbons are perpendicular
to the square plane of the complex (Pt,
P, & CH3 atoms)
Complex B
Ph3P
PPH3
CI
Pt-PR3 = 2.28 A
Pt-alkyne = 2.05 Á
C=C = 1.38 Â
Me-C=C = 134°
Alkyne carbons are in the square
plane of the complex

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