1. Suppose you were doing two related SNAR syntheses in lab. Draw the product of mono- substitution with the aryl amine showl. NH2 (A) ELOH, 10 mL per mmole NET,, 1 molar equivalent O,N `NO2 NH, (В) ELOH, 5 mL per mmole NET,, 1 molar equivalent `NO, Two products possible -- draw either one and assume it's the ONLY product Reaction (A): MW, g/mol ВР, °С Density, g/mL Amount, moles Amount, g or mL solid XXX 1.00 g ON NO, NH, 93.13 184 1.02 mL 10 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL Reaction (B): MW, g/mol BP, °C Density, g/mL | Amount, moles Amount, g or mL solid XXX 1.00 g `NO, NH, 219.02 Solid XXX g 5 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL (b) Suppose that after recrystallization, you magically got 0.500 g of product from each reaction. What is vour % vield in each case?

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1. Suppose you were doing two related SNAr syntheses in lab. Draw the product of mono-
substitution with the aryl amine shown.
NH,
+
(A)
EtOН, 10 mL
NET3, 1 molar equivalent
per
mmole
O,N
'NO,
F.
F
NH2
(B)
ELOH, 5 mL per mmole
NET3, 1 molar equivalent
`NO,
Two products possible -- draw either one
and assume it's the ONLY product
Reaction (A):
MW, g/mol
ВР, "С
Density, g/mL Amount, moles
Amount, g or mL
solid
XXX
1.00 g
`NO2
NH2
O,N
93.13
184
1.02
mL
10 mL per
ELOH
46.07
78
0.789
mL
mmole
NET3
101.19
89
0.726
mL
Reaction (B):
MW, g/mol
ВР, "С
Density, g/mL | Amount, moles
Amount, g or mL
solid
XXX
1.00 g
`NO2
NH,
219.02
Solid
XXX
5 mL per
ELOH
46.07
78
0.789
mL
mmole
NET3
101.19
89
0.726
mL
(b) Suppose that after recrystallization, you magically got 0.500 g of product from each reaction.
What is your % yield in each case?
Transcribed Image Text:1. Suppose you were doing two related SNAr syntheses in lab. Draw the product of mono- substitution with the aryl amine shown. NH, + (A) EtOН, 10 mL NET3, 1 molar equivalent per mmole O,N 'NO, F. F NH2 (B) ELOH, 5 mL per mmole NET3, 1 molar equivalent `NO, Two products possible -- draw either one and assume it's the ONLY product Reaction (A): MW, g/mol ВР, "С Density, g/mL Amount, moles Amount, g or mL solid XXX 1.00 g `NO2 NH2 O,N 93.13 184 1.02 mL 10 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL Reaction (B): MW, g/mol ВР, "С Density, g/mL | Amount, moles Amount, g or mL solid XXX 1.00 g `NO2 NH, 219.02 Solid XXX 5 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL (b) Suppose that after recrystallization, you magically got 0.500 g of product from each reaction. What is your % yield in each case?
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