1. Suppose you were doing two related SNAR syntheses in lab. Draw the product of mono- substitution with the aryl amine showl. NH2 (A) ELOH, 10 mL per mmole NET,, 1 molar equivalent O,N `NO2 NH, (В) ELOH, 5 mL per mmole NET,, 1 molar equivalent `NO, Two products possible -- draw either one and assume it's the ONLY product Reaction (A): MW, g/mol ВР, °С Density, g/mL Amount, moles Amount, g or mL solid XXX 1.00 g ON NO, NH, 93.13 184 1.02 mL 10 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL Reaction (B): MW, g/mol BP, °C Density, g/mL | Amount, moles Amount, g or mL solid XXX 1.00 g `NO, NH, 219.02 Solid XXX g 5 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL (b) Suppose that after recrystallization, you magically got 0.500 g of product from each reaction. What is vour % vield in each case?
1. Suppose you were doing two related SNAR syntheses in lab. Draw the product of mono- substitution with the aryl amine showl. NH2 (A) ELOH, 10 mL per mmole NET,, 1 molar equivalent O,N `NO2 NH, (В) ELOH, 5 mL per mmole NET,, 1 molar equivalent `NO, Two products possible -- draw either one and assume it's the ONLY product Reaction (A): MW, g/mol ВР, °С Density, g/mL Amount, moles Amount, g or mL solid XXX 1.00 g ON NO, NH, 93.13 184 1.02 mL 10 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL Reaction (B): MW, g/mol BP, °C Density, g/mL | Amount, moles Amount, g or mL solid XXX 1.00 g `NO, NH, 219.02 Solid XXX g 5 mL per ELOH 46.07 78 0.789 mL mmole NET3 101.19 89 0.726 mL (b) Suppose that after recrystallization, you magically got 0.500 g of product from each reaction. What is vour % vield in each case?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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