1. State if there is an angular momentum contribution to the Heff of [Mn(OH2)6]²+ knowing that the measured Heff = 5.92 μв at 300 K. Show your reasoning. Hint: consider whether the complex is high- or low-spin. Oxi = 2-0 =2, dm =>ds, high spin 2. Which species, among the one listed below, is likely to be the most stable with respect to oxidation and reduction? Explain your choice. -a) Mn(VII) b) Fe(VI) 8-6=2 c) W(III) d) Mo(VI) e) Cr(VI) 6-3=3 6-6=0 6-6=0

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1. State if there is an angular momentum contribution to the Heff of [Mn(OH₂)6]²+ knowing
that the measured Heff = 5.92 μB at 300 K. Show your reasoning. Hint: consider whether
the complex is high- or low-spin.
Oxi = 2-0 =2, dm =>ds, high spin
2. Which species, among the one listed below, is likely to be the most stable with respect to
oxidation and reduction? Explain your choice.
O-a) Mn(VII)
b) Fe(VI) 8-6-2
c) W(III)
d) Mo(VI)
e) Cr(VI)
6-3=3
6-6=0
6-6=0
Transcribed Image Text:1. State if there is an angular momentum contribution to the Heff of [Mn(OH₂)6]²+ knowing that the measured Heff = 5.92 μB at 300 K. Show your reasoning. Hint: consider whether the complex is high- or low-spin. Oxi = 2-0 =2, dm =>ds, high spin 2. Which species, among the one listed below, is likely to be the most stable with respect to oxidation and reduction? Explain your choice. O-a) Mn(VII) b) Fe(VI) 8-6-2 c) W(III) d) Mo(VI) e) Cr(VI) 6-3=3 6-6=0 6-6=0
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