1. Propose reasonable synthetic pathways for the conversion of 1-butanol into the various products.Building blocks (reagents) that introduce one carbon atom (or other skeletal atom) may be assumed asbeing readily available.NH2OHOHOMeOHCO₂

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Answered: 1. Propose reasonable synthetic…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.55P

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Aldehydes and ketones react with one molecule of an alcohol to form compounds called hemiacetals, in which there is one hydroxyl group and one ether-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction in Chapter 16. Draw structural formulas for the hemiacetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.
Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.
Give the systematic (IUPAC) names for these molecules. Boononon cnolonongron. НаСНз CHОССH2СH2СНCHЗ CH3 phenyl propanoate |4-methyl pentane methanoat Incorrect. You mixed up the acyl and alkoxy portions of the molecule. Name the alkoxy part first, followed by the acyl part.
Provide the major organic products for the following reactions.
2
4) Give an example of an enol which would tautomerize into a) an aldehyde and b) a ketone.
Draw the overall reaction of 1-butanol with HBr and H2SO4 to form 1-bromobutane.
Provide the major organic product of the following reaction.
10) For the reaction between isopropyl 1-propyl (or 'n-propyl') ether and HBr, which type of reaction best matches the expected products? A) Acid-catalyzed dehydration B) Nucleophilic substitution reaction C) Ether cleavage reaction D) Nucleophilic addition-elimination reaction
Explain why methyl trifluoroacetate, CF3CO2CH3, is more reactive than methyl acetate, CH3CO2CH3, in nucleophilic acyl substitution reactions.
Provide the major organic product of the following reaction. H3O', heat
Starting from cyclohexanone, show how to make the given product, include conditions to use in the reaction. HaG CH3 ཡིག་..སྟན་ཚིག་

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1. Propose reasonable synthetic pathways for the conversion of 1-butanol into the various products. Building blocks (reagents) that introduce one carbon atom (or other skeletal atom) may be assumed as being readily available. NH2 OH OH OMe OH CO₂