1. M. Hellin and J. C. Jungers, Bull. soc. chim. France, 386 (1957), present the data in table below on the reaction of sulfuric acid with diethylsulfate in aqueous solution at 22.9°C: H2SO4 + (C2H5)2SO4 → 2C2H$SO4H Initial concentrations of H2SO4 and (C2H5)2SO4 are each 5.5 mol/liter. Find a rate equation for this reaction. (Levenspiel 3.20) t, min C2H5SO4H, mol/L t, min C2H5SO4H, mol/L 180 4.11 41 1.18 194 4.31 48 1.38 212 4.45 55 1.63 267 4.86 75 2.24 318 5.15 96 2.75 368 5.32 127 3.31 379 5.35 146 3.76 410 5.42 162 3.81 (5.80)

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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  1. Hellin and J. C. Jungers, Bull. soc. chim. France, 386 (1957), present the data in table below on the reaction of sulfuric acid with diethylsulfate in aqueous solution at 22.9oC:

 

H2SO4 + (C2H5)2SO4 à 2C2H5SO4H

 

Initial concentrations of H2SO4 and (C2H5)2SO4 are each 5.5 mol/liter. Find a rate equation for this reaction. (Levenspiel 3.20)

1. M. Hellin and J. C. Jungers, Bull. soc. chim. France, 386 (1957), present the
data in table below on the reaction of sulfuric acid with diethylsulfate in
aqueous solution at 22.9°C:
H2SO4 + (C2H5)2SO4 → 2C2H$SO,H
Initial concentrations of H2SO4 and (C2H5)2SO4 are each 5.5 mol/liter. Find
a rate equation for this reaction. (Levenspiel 3.20)
t, min
C2H5SO4H, mol/L
t, min
C2H5SO4H, mol/L
180
4.11
41
1.18
194
4.31
48
1.38
212
4.45
55
1.63
267
4.86
75
2.24
318
5.15
96
2.75
368
5.32
127
3.31
379
5.35
146
3.76
410
5.42
162
3.81
(5.80)
Transcribed Image Text:1. M. Hellin and J. C. Jungers, Bull. soc. chim. France, 386 (1957), present the data in table below on the reaction of sulfuric acid with diethylsulfate in aqueous solution at 22.9°C: H2SO4 + (C2H5)2SO4 → 2C2H$SO,H Initial concentrations of H2SO4 and (C2H5)2SO4 are each 5.5 mol/liter. Find a rate equation for this reaction. (Levenspiel 3.20) t, min C2H5SO4H, mol/L t, min C2H5SO4H, mol/L 180 4.11 41 1.18 194 4.31 48 1.38 212 4.45 55 1.63 267 4.86 75 2.24 318 5.15 96 2.75 368 5.32 127 3.31 379 5.35 146 3.76 410 5.42 162 3.81 (5.80)
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