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1. In the Diels-Alder reaction below, six isomeric products A-F are depicted. However, only one of these is the major product formed. OMe OMe CN CN OMe "Me Me Me Me OMe OMe OMe Me Me CN CN GN D E a) In the boxes above, label the diene and dienophile. b) Identify the two isomers that are unreasonable based on the concerted mechanism of the Diels-Alder reaction. (Hint: look at the geometry of the dienophile) Isomers: and c) Label the four remaining isomers as either endo or exo products. Endo: and Exo: and

1. In the Diels-Alder reaction below, six isomeric products A-F are depicted. However, only one of these is the major product formed. OMe OMe CN CN OMe "Me Me Me Me OMe OMe OMe Me Me CN CN GN D E a) In the boxes above, label the diene and dienophile. b) Identify the two isomers that are unreasonable based on the concerted mechanism of the Diels-Alder reaction. (Hint: look at the geometry of the dienophile) Isomers: and c) Label the four remaining isomers as either endo or exo products. Endo: and Exo: and

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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T TrineOniline | Trine U in CH---214-01-5P-202 x E Problem Set 8.pdf 0 Mail - Outwater, Peri: X C Solvent Free Reduct x A New teb A Adobe Scan Apr 26. O File | CUsers/paris/Downloads/Problem%20Set%208.pdf 1 O A Page view A* Read aloud V Draw E Highlight v O Erase of 1 O Add text 1. In the Diels-Alder reaction below, six isomeric products A-F are depicted. However, only one of these is the major product formed. CM: OMe OMe CN .CN .CN OMe "Ma Me Ma CN OMs OMe OMe Me Me Me GN 'CN ON D E a) In the boxes above, label the diene and dienophile. b) Identify the two isomers that are unreasonable based on the concerted mechanism of the Diels-Alder reaction. (Hint: look at the geometry of the dienophile) Isomers: and c) Label the four remaining isomers as either endo or exo products. Endo: and Exo: and d) Of the two endo products, which would you predict to be favored based on regio- chemistry electronics? Explain your choice using resonance structures for full credit. Major Product: 41"F 2:05 PM Cloudy 4/26/2022
Transcribed Image Text:T TrineOniline | Trine U in CH---214-01-5P-202 x E Problem Set 8.pdf 0 Mail - Outwater, Peri: X C Solvent Free Reduct x A New teb A Adobe Scan Apr 26. O File | CUsers/paris/Downloads/Problem%20Set%208.pdf 1 O A Page view A* Read aloud V Draw E Highlight v O Erase of 1 O Add text 1. In the Diels-Alder reaction below, six isomeric products A-F are depicted. However, only one of these is the major product formed. CM: OMe OMe CN .CN .CN OMe "Ma Me Ma CN OMs OMe OMe Me Me Me GN 'CN ON D E a) In the boxes above, label the diene and dienophile. b) Identify the two isomers that are unreasonable based on the concerted mechanism of the Diels-Alder reaction. (Hint: look at the geometry of the dienophile) Isomers: and c) Label the four remaining isomers as either endo or exo products. Endo: and Exo: and d) Of the two endo products, which would you predict to be favored based on regio- chemistry electronics? Explain your choice using resonance structures for full credit. Major Product: 41"F 2:05 PM Cloudy 4/26/2022
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