9. At what position, and on what ring, would you expect the following substances to undergo electrophilic substitution? H "oa "bra "oko" a) CH3 b) Br c)
9. At what position, and on what ring, would you expect the following substances to undergo electrophilic substitution? H "oa "bra "oko" a) CH3 b) Br c)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question 9:**
At what position, and on what ring, would you expect the following substances to undergo electrophilic substitution?
**a)** This compound has a structure with two benzene rings connected by an ether linkage (an oxygen atom), with one of the rings having a methyl group (CH₃) attached to it.
**b)** This compound consists of two benzene rings connected by an amine linkage (a nitrogen atom with hydrogen). A bromine atom (Br) is attached to one of the benzene rings.
**c)** This compound features two benzene rings connected by a ketone linkage (a carbonyl group), with a chlorine atom (Cl) attached to one of the benzene rings.
*Graphical Explanation:*
- **a)** The ether linkage (O) is connecting the two benzene rings, and a methyl group is directly attached to one of the rings potentially activating it for substitution.
- **b)** The amine linkage (NH) connects two benzene rings, while a bromine atom is attached to one of the rings, affecting its reactivity in electrophilic substitution.
- **c)** The presence of the carbonyl group (C=O) serves as a linkage between two benzene rings, with a chlorine atom connected to one of the rings, influencing its chemical behavior.
Consider how the substituents and linkages influence electron density on each benzene ring for electrophilic substitution predictions.
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