If resonance exists, provide all resonance structures for the following carbocation: HN a) If the carbocation were to react with a Nucleophile, at which position(s) will the reaction take place?
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- When propene reacts with gaseous hydrogen bromide, HBr, two products, 1-bromopropane and 2-bromopropane are formed. The reaction is a two-step process in which the electrophilic attack occurs in the first step. Identify the electrophile in this reaction Draw a diagram showing the first step of the reaction that leads to the production of 2-bromopropane.Answer the following questions based on the data givenAn electron-deficient carbon atom reacts with a nucleophile, symbolized as: Nu−. Define this ?
- Draw a Lewis structure of sodium ethyl mercaptide (NaSC2H5), showing all relevant lone pairs and formal charges. Based on the structure you drew, do you expect that it would act as a good nucleophile? Do you expect it to act as a strong base?1) The carbon-oxygen double bond present in aldehydes and ketones is very polar. What does this mean and how does it arise? 2) The carbon-oxygen double bond is readily attacked by nucleophiles like cyanide ions or ammonia. (i) What do you understand by the term nucleophile? (ii) Which part of the carbon-oxygen double bond is attractive to nucleophiles? 3) Why is there a difference between aldehydes and ketones in their response to oxidizing agents such as potassium dichromate(VI) solution acidified with dilute sulfuric acid?5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH,CH,CH,CH,CCH, Br b) For the major elimination product obtained in 5a), which stereoisonmer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.
- Nitration of an aromatic ring involves an electrophilic substitution reaction. Draw the structure of the electrophile that is attacked by the aromatic ring and the intermediate formed after attachment of the electrophile to the ring. Be sure to show formal charges.what will be the type of interaction of ethane with bromine: a) radicals b) ionic c) nucleophilic d) electrophilicThe following reaction can be described by a THREE step mechanism. A drawing of the energy diagram for this reaction is shown below. OH H, SO4 В A Reaction coordinate (i) Write out the three steps in this mechanism. For each step, draw structures for the reactants and products and curved arrows to show bonds formed and bonds broken. (ii) Indicate which of the drawings in your mechanism corresponds to points A, B and C on the energy diagram. Draw the structure of the MAJOR product in the following reaction and an arrow pushing reaction mechanism to showhow the product is formed. H;O+ Potential energy
- Complete the following reaction with explanationH3C CH3 H3C NA C→XT Br Br₂ CH₂Cl₂ H3C Electrophilic addition of bromine, Br₂, to alkenes yields a 1,2-dibromoalkane. The reaction proceeds through a cyclic intermediate known as a bromonium ion. The reaction occurs in an anhydrous solvent such as CH₂Cl₂. CH3 Br In the second step of the reaction, bromide is the nucleophile and attacks at one of the carbons of the bromonium ion to yield the product. Due to steric clashes, the bromide ion always attacks the carbon from the opposite face of the bromonium ion so that a product with anti stereochemistry is formed. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Br CH3 H3C CH3Decide whether the reactions below will proceed via an SN1 or SN2 mechanism. (b) Draw structural formula form the major organic products only
