1. Draw the possible ionization states for each of the following amino acids and label each structure (A, B, C, etc.). Indicate the predominant ionization state at pH = 1, 3, pI, 7, 11 (write the letter designation only). a.) arginine Predominant ionization state: pH 1-_; pH 3-___; pI-_; pH 7-_; pH 11- b.) tyrosine Predominant ionization state: pH 1-___; pH 3-_; pI-_; pH 7-; pH 11-_ 2. Draw the structure of the following peptides at the indicated pH and give the name of each. Conventionally, the first residue is the N-terminal amino acid (i.e. it has a free -amino group). a.) the dipeptide Arg-Cys (at pH equal to 7.0) b.) the tripeptide Asp-Val-Asn (at pH equal to 10.0)
1. Draw the possible ionization states for each of the following amino acids and label each structure (A, B, C, etc.). Indicate the predominant ionization state at pH = 1, 3, pI, 7, 11 (write the letter designation only). a.) arginine Predominant ionization state: pH 1-_; pH 3-___; pI-_; pH 7-_; pH 11- b.) tyrosine Predominant ionization state: pH 1-___; pH 3-_; pI-_; pH 7-; pH 11-_ 2. Draw the structure of the following peptides at the indicated pH and give the name of each. Conventionally, the first residue is the N-terminal amino acid (i.e. it has a free -amino group). a.) the dipeptide Arg-Cys (at pH equal to 7.0) b.) the tripeptide Asp-Val-Asn (at pH equal to 10.0)
General, Organic, and Biological Chemistry
7th Edition
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:H. Stephen Stoker
Chapter20: Proteins
Section: Chapter Questions
Problem 20.58EP: For the tripeptide SerValMet a. What amino acid is located at the peptides N-terminal end? b. What...
Related questions
Question
#1- Show the complete protonic equilibria and the calculation of IpH.
#2- Don't have to show the complete protonic equilibria. Just show the structure of the peptide at the specified pH.
*Do not use skeletal formulas when drawing the structures*
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps
Recommended textbooks for you
General, Organic, and Biological Chemistry
Chemistry
ISBN:
9781285853918
Author:
H. Stephen Stoker
Publisher:
Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:
9781305081079
Author:
STOKER, H. Stephen (howard Stephen)
Publisher:
Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:
9781285853918
Author:
H. Stephen Stoker
Publisher:
Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:
9781305081079
Author:
STOKER, H. Stephen (howard Stephen)
Publisher:
Cengage Learning,
Introductory Chemistry: A Foundation
Chemistry
ISBN:
9781337399425
Author:
Steven S. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning